Skip to main content
SpringerLink
Log in

Electronic spectral study of the interaction of CoNaX zeolite with C1−C5 hydrocarbons

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Interaction of both satured and unsaturated hydrocarbons with tetrahedral Co2+ ion complexes lodged in the zeolite skeleton is reported on the basis of diffuse reflectance spectra. While saturated hydrocarbons do not affect the coordination sphere of the Co-complex, the unsaturated hydrocarbons change considerably the distortion of the tetrahedral Co-complex.

Abstract

Приведены результаты изучения спектров диффузионного отражения при взаимодействии насыщенных и ненасы-щенных углеводородов с тетраэдрическими Co2+ ком-плексами внедрёнными в скелете цеолита. В то время как насыщенные углеводороды не влияют на координа-ционную сферу Co-комплексов, ненасыщенные углево-дороды сушественно изменяют искажение тетраэдри-ческого Co-комплекса.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Kubelková, B. Wichterlová: Coll. Czech. Chem. Commun. (In press)

  2. B. Wichterlová, P. Jírů, A. Cuřínová: Z. Phys. Chem., N. F.,88, 180 (1974).

    Google Scholar 

  3. I. D. Mikheikin, O. I. Brotikovskii, G. M. Zhidomirov, V. B. Kazanskii: Kinet. Katal.,12, 1442 (1971).

    Google Scholar 

  4. V. A. Heilbron, J. C. Vickerman: J. Catal.,33, 434 (1974).

    Google Scholar 

  5. J. Ferguson, D. L. Wood, L. G. van Uitert: J. Chem. Phys.,51, 2904 (1969).

    Google Scholar 

  6. F. A. Cotton, D. M. L. Goodgame, M. Goodgame: J. Amer. Chem. Soc.,83, 4690 (1961).

    Google Scholar 

  7. M. D. Sturge: Solid State Phys.,20, 207 (1967).

    Google Scholar 

  8. I. B. Bersuker: Coord. Chem. Rev.,14, 357 (1975).

    Google Scholar 

  9. D. Michel, W. Meiler, H. Pfeifer: J. Mol. Catal.,1, 85 (1975).

    Google Scholar 

  10. L. Kubelková, J. Nováková, M. Křivánek, P. Jírů: React. Kinet. Catal. Lett. (In press)

  11. J. Nováková, L. Kubelková, P. Jírů: Coll. Czech. Chem. Commun. (In press)

  12. K. Klier, R. Kellerman, P. J. Hutta: J. Chem. Phys.,61, 4224 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 121 38, Prague 2, Czechoslovakia

    B. Wichterlová, S. Beran & P. Jírů

Authors
  1. B. Wichterlová
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Beran
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Jírů
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wichterlová, B., Beran, S. & Jírů, P. Electronic spectral study of the interaction of CoNaX zeolite with C1−C5 hydrocarbons. React Kinet Catal Lett 5, 367–372 (1976). https://doi.org/10.1007/BF02063049

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02063049

Keywords

Search

Navigation