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Reaction Kinetics and Catalysis Letters

, Volume 5, Issue 3, pp 367–372 | Cite as

Electronic spectral study of the interaction of CoNaX zeolite with C1−C5 hydrocarbons

  • B. Wichterlová
  • S. Beran
  • P. Jírů
Article
  • 14 Downloads

Abstract

Interaction of both satured and unsaturated hydrocarbons with tetrahedral Co2+ ion complexes lodged in the zeolite skeleton is reported on the basis of diffuse reflectance spectra. While saturated hydrocarbons do not affect the coordination sphere of the Co-complex, the unsaturated hydrocarbons change considerably the distortion of the tetrahedral Co-complex.

Keywords

Physical Chemistry Zeolite Catalysis Hydrocarbon Reflectance Spectrum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Приведены результаты изучения спектров диффузионного отражения при взаимодействии насыщенных и ненасы-щенных углеводородов с тетраэдрическими Co2+ ком-плексами внедрёнными в скелете цеолита. В то время как насыщенные углеводороды не влияют на координа-ционную сферу Co-комплексов, ненасыщенные углево-дороды сушественно изменяют искажение тетраэдри-ческого Co-комплекса.

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Copyright information

© Akadémiai Kiadó 1976

Authors and Affiliations

  • B. Wichterlová
    • 1
  • S. Beran
    • 1
  • P. Jírů
    • 1
  1. 1.J. Heyrovský Institute of Physical Chemistry and ElectrochemistryCzechoslovak Academy of SciencesPrague 2Czechoslovakia

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