Reaction Kinetics and Catalysis Letters

, Volume 5, Issue 3, pp 367–372 | Cite as

Electronic spectral study of the interaction of CoNaX zeolite with C1−C5 hydrocarbons

  • B. Wichterlová
  • S. Beran
  • P. Jírů


Interaction of both satured and unsaturated hydrocarbons with tetrahedral Co2+ ion complexes lodged in the zeolite skeleton is reported on the basis of diffuse reflectance spectra. While saturated hydrocarbons do not affect the coordination sphere of the Co-complex, the unsaturated hydrocarbons change considerably the distortion of the tetrahedral Co-complex.


Physical Chemistry Zeolite Catalysis Hydrocarbon Reflectance Spectrum 
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Приведены результаты изучения спектров диффузионного отражения при взаимодействии насыщенных и ненасы-щенных углеводородов с тетраэдрическими Co2+ ком-плексами внедрёнными в скелете цеолита. В то время как насыщенные углеводороды не влияют на координа-ционную сферу Co-комплексов, ненасыщенные углево-дороды сушественно изменяют искажение тетраэдри-ческого Co-комплекса.


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Copyright information

© Akadémiai Kiadó 1976

Authors and Affiliations

  • B. Wichterlová
    • 1
  • S. Beran
    • 1
  • P. Jírů
    • 1
  1. 1.J. Heyrovský Institute of Physical Chemistry and ElectrochemistryCzechoslovak Academy of SciencesPrague 2Czechoslovakia

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