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Reaction Kinetics and Catalysis Letters

, Volume 28, Issue 2, pp 301–306 | Cite as

Anion-radical formation in the adsorption of thiophene and its derivatives on H-mordenite

  • A. V. Kucherov
  • A. A. Slinkin
  • V. P. Litvinov
Article

Abstract

For the first time it has been established that the adsorption of thiophene and its derivatives on H-mordenite provides individual ESR signals with an hyperfine structure. A comparison of the experimental ESR spectra with the calculated magnetic resonance parameters permits to suggest that during the adsorption on HM anion-radicals of thiophene and its derivatives are formed.

Keywords

Physical Chemistry Catalysis Thiophene Resonance Parameter Hyperfine Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Впервые показано, что адсорбция на HM тиофена и его производных сопровождается формированием индивидуальных спектров ЭПР с СТС. Сопоставление спектров ЭПР с результатами квантовохимических расчетов позволяет заключить, что при адсорбции на HM образуются анион-радикалы тиофена и его производных.

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References

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Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • A. V. Kucherov
    • 1
  • A. A. Slinkin
    • 1
  • V. P. Litvinov
    • 1
  1. 1.Institute of Organic ChemistryMoscowUSSR

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