Reaction Kinetics and Catalysis Letters

, Volume 28, Issue 2, pp 287–293 | Cite as

Gel-immobilized catalytic systems for propylene dimerization containing organophosphorus ligands

  • G. P. Potapov
  • V. A. Shepelin


Catalytic dimerization of propylene in the presence of macromolecular nickel complexes containing organophosphorus ligands has been studied. It has been established that the substitution of alkoxy groups of phosphorus atoms in the polymeric ligands does not affect the dimer composition but permits, within certain limits, to control catalyst activity.


Physical Chemistry Nickel Phosphorus Catalysis Propylene 
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Изучена каталитическая димеризация пропилена в присутствии макромолекулярных комплексов никеля, содержащих фосфорорганические лиганды. Показано, что замена алкоксильных радикалов у атома фосфора в полимерном лиганде практически не влияет на димерный состав, но позволяет в некоторых пределах регулировать активность катализаторов.


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Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • G. P. Potapov
    • 1
  • V. A. Shepelin
    • 1
  1. 1.State UniversitySyktyvkarUSSR

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