Reaction Kinetics and Catalysis Letters

, Volume 31, Issue 1, pp 151–158 | Cite as

Influence of rare earth ions on the properties of Pd/SiO2 in CO hydrogenation

  • Yu. A. Ryndin
  • Yu. N. Nogin
  • Yu. B. Zverev
  • N. P. Chernyaev
  • F. G. Abdikova
  • Yu. I. Yermakov
Article

Abstract

Systematic studies of the effect of the lanthanoid (Ln) nature on the activity and selectivity of (Pd+Ln)/SiO2 catalysts obtained by decomposition of anchored Ln and Pd complexes in methanol synthesis from CO and H2 have been carried out. It has been established that the highest promoting effect is observed for Pr and Ho ions.

Keywords

Hydrogenation Methanol Physical Chemistry SiO2 Catalysis 

Abstract

Выполнено систематическое изучение влияния природы лантаноида (Ln) на активность и селективность (Pd+Ln)/SiO2 катализаторов, полученных разложением закрепленных комплексов Ln и Pd, в реакции синтеза метанола из CO и H2. Наибольшим промотирующим действием обладут ионы Pr и Ho.

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Copyright information

© Akadémiai Kiadó 1986

Authors and Affiliations

  • Yu. A. Ryndin
    • 1
  • Yu. N. Nogin
    • 1
  • Yu. B. Zverev
    • 1
  • N. P. Chernyaev
    • 1
  • F. G. Abdikova
    • 1
  • Yu. I. Yermakov
    • 1
  1. 1.Institute of CatalysisNovosibirskUSSR

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