Skip to main content
SpringerLink
Log in

Reactivity of electronically excited Br(2P1/2) atoms towards CH3F

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The rate constants for Br(2P1/2) and Br(2P3/2) atoms in the reaction Br+CH3F→HBr+CH2F in photobromination of CH3F have been determined. Their ratio is 10−(2.6±0.5) exp(10100±1000/RT) in the temperature range of 60–200 °C.

Abstract

Определены константы скоростей атомов Br(2P1/2) и Br(2P3/2) в реакции Br+CH3F→HBr+CH2F при фотобромировании CH3F. Их отношение в температурном интервале 60–200 °C равно 10−(2,6±0,5) exp (10100±1000/RT).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. A. Coxon: Molecular Spectroscopy, vol. 1, p. 177. Chemical Society, London 1973.

    Google Scholar 

  2. J. Yguerabide: Rev. Sci. Instrum.,39, 7, 1048 (1968).

    Google Scholar 

  3. P. Sulzer, K. Wieland: Helv. Phys. Acta,25, 653 (1952).

    Google Scholar 

  4. A. A. Passchier, J. D. Christian, N. W. Gregory: J. Phys. Chem.,71, 937 (1967).

    Google Scholar 

  5. A. Hariri, A. B. Peterson, C. Wittig: J. Chem. Phys.,65, 1872 (1976).

    Google Scholar 

  6. A. B. Callier, J. F. Wilson: Trans. Faraday Soc.,63, 1358, 1983 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Novosibirsk, USSR

    L. N. Krasnopyorov, N. K. Serdyuk, V. P. Strunin & V. N. Panfilov

Authors
  1. L. N. Krasnopyorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. K. Serdyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Strunin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Panfilov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krasnopyorov, L.N., Serdyuk, N.K., Strunin, V.P. et al. Reactivity of electronically excited Br(2P1/2) atoms towards CH3F. React Kinet Catal Lett 7, 321–326 (1977). https://doi.org/10.1007/BF02062463

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02062463

Keywords

Search

Navigation