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Study of selective dissociation in C6F5H−C6F5D mixtures induced by intense CO2 laser pulses

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Abstract

Irradiation of a C6F5H−C6F5D mixture at 1 Torr by a tunable CO2 pulse laser brings about chiefly dissociation of one component depending on the frequency of emission absorbed by the proper molecules. The addition of radical acceptors increases the selectivity by suppressing secondary reactions.

Abstract

Действуя на смесь газов C6F5H и C6F5D при давлении ∼1 тор импульсным и перестраиваемым по частоте CO2-лазером, удалось преимущественно диссоциировать с образованием радикалов одну из компонент смеси в зависимости от частоты излучения, резонансно поглощаемого соответствующими молекулами. Добавка акцепторов радикалов увеличивает селективность за счёт уменьшения канала вторичных реакций.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Institute of Semiconductors, Novosibirsk, USSR

    V. V. Vizhin, Yu. N. Molin, A. K. Petrov, V. N. Lisitsyn & A. R. Sorokin

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  1. V. V. Vizhin
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  2. Yu. N. Molin
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  3. A. K. Petrov
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  4. V. N. Lisitsyn
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  5. A. R. Sorokin
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Vizhin, V.V., Molin, Y.N., Petrov, A.K. et al. Study of selective dissociation in C6F5H−C6F5D mixtures induced by intense CO2 laser pulses. React Kinet Catal Lett 7, 303–307 (1977). https://doi.org/10.1007/BF02062460

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  • DOI: https://doi.org/10.1007/BF02062460

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