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Acetoxylation of olefins catalyzed by a palladium(II)-heteropolyacid system

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Abstract

The catalytic acetoxylation of ethylene and propylene occurs under the action of oxygen in the presence of Pd(II)+HPA-6, where HPA-6 is the heteropolyacid H9PMo6V6O40. In addition to the products of acetoxylation (alkenyl and allyl acetates), oxidation products (acetaldehyde and acetone) are also formed. The selectivity of acetoxylation increases upon the addition of NaOAc.

Abstract

Показана возможность каталитического ацетоксилирования олефинов — этилена и пропилена — под действием кислорода в присутствии катализатора Pd(II)+ГПК-6, где ГПК-6 фосфорномолибдованадиевая гетерополикислота H9PMo6V6O40. Наряду с продуктами ацетоксилирования (алкенил- и аллилацетаты) образуются продукты окисления — ацетальдегид и ацетон. Селективность реакции ацетоксилирования возрастает при добавках NaOAc.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    I. V. Kozhevnikov, V. E. Taraban'ko, K. I. Matveev & V. D. Vardanyan

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  1. I. V. Kozhevnikov
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  2. V. E. Taraban'ko
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  3. K. I. Matveev
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  4. V. D. Vardanyan
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Kozhevnikov, I.V., Taraban'ko, V.E., Matveev, K.I. et al. Acetoxylation of olefins catalyzed by a palladium(II)-heteropolyacid system. React Kinet Catal Lett 7, 297–302 (1977). https://doi.org/10.1007/BF02062459

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  • DOI: https://doi.org/10.1007/BF02062459

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