Reaction Kinetics and Catalysis Letters

, Volume 15, Issue 1, pp 49–54 | Cite as

Kinetics of arylation of olefins by Pd(OAc)2 in benzene

  • I. V. Kozhevnikov
  • S. Ts. Sharapova
Article

Abstract

Kinetics of phenylation of ethylene and styrene by Pd(OAc)2 in benzene at 95 °C is described by the equation W=k [PdII][PhH][Ol], kC2H4/kC2D4= =1.2±0.2, kPhH/kPhD=5.0±0.5. The reaction mechanism is discussed.

Keywords

Ethylene Physical Chemistry Benzene Catalysis Styrene 

Abstract

Кинетика фенилирования этилена и стирола под действнем Pd(OAc)2 в бензоле при 95 °C соответствует уравнению W=k[PdII][PhH][ол]kC2H4/kC2D4=1,2±0,2, kPhH/kPhD=5,0±0,5. Обусждается механизм.

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Copyright information

© Akadémiai Kiadó 1980

Authors and Affiliations

  • I. V. Kozhevnikov
    • 1
  • S. Ts. Sharapova
    • 1
  1. 1.Institute of CatalysisNovosibirskUSSR

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