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Reaction Kinetics and Catalysis Letters

, Volume 15, Issue 1, pp 49–54 | Cite as

Kinetics of arylation of olefins by Pd(OAc)2 in benzene

  • I. V. Kozhevnikov
  • S. Ts. Sharapova
Article

Abstract

Kinetics of phenylation of ethylene and styrene by Pd(OAc)2 in benzene at 95 °C is described by the equation W=k [PdII][PhH][Ol], kC2H4/kC2D4= =1.2±0.2, kPhH/kPhD=5.0±0.5. The reaction mechanism is discussed.

Keywords

Ethylene Physical Chemistry Benzene Catalysis Styrene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Кинетика фенилирования этилена и стирола под действнем Pd(OAc)2 в бензоле при 95 °C соответствует уравнению W=k[PdII][PhH][ол]kC2H4/kC2D4=1,2±0,2, kPhH/kPhD=5,0±0,5. Обусждается механизм.

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Copyright information

© Akadémiai Kiadó 1980

Authors and Affiliations

  • I. V. Kozhevnikov
    • 1
  • S. Ts. Sharapova
    • 1
  1. 1.Institute of CatalysisNovosibirskUSSR

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