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Interaction of trimethylchlorosilane with silanol groups silica surface in the presence of amines

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Abstract

Experimental and quantum chemical studies of ClSi(CH3)3 interactions with ≡SiOH groups catalyzed by amines were carried out using aerosil samples. The catalytic effects are due to the enthalpy factor of rate constants through transition state stabilization by NR3.

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Authors and Affiliations

  1. Institute of Surface Chemistry, Ukrainian Academy of Sciences, Kiev, Ukraine

    E. M. Pakhlov, V. M. Gun'ko & E. F. Voronin

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  1. E. M. Pakhlov
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  2. V. M. Gun'ko
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  3. E. F. Voronin
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Pakhlov, E.M., Gun'ko, V.M. & Voronin, E.F. Interaction of trimethylchlorosilane with silanol groups silica surface in the presence of amines. React Kinet Catal Lett 50, 305–310 (1993). https://doi.org/10.1007/BF02062228

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