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Reactions of gaseous organic compounds on silica surface. Spectral studies and synthetic aspects

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Abstract

The results of infrared spectroscopic and mass-spectrometric studies on reactions of vapor phase carboxylic acids, polyazamacrocyclic ligands, pyrimidine bases, acetylacetonates and related compounds with hydroxylic, chlorosilylated, halo- and aminoalkylsilylated silica surfaces are analyzed. Application of various reactions for the gasphase derivatization of silica materials and for the “gassolid-phase” synthesis of 2,5-dioxoperazines is discussed.

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Authors and Affiliations

  1. Institute of Surface Chemistry, Ukrainian Academy of Sciences, Kiev, Ukraine

    Vladimir A. Basyuk

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  1. Vladimir A. Basyuk
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Basyuk, V.A. Reactions of gaseous organic compounds on silica surface. Spectral studies and synthetic aspects. React Kinet Catal Lett 50, 83–88 (1993). https://doi.org/10.1007/BF02062193

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