Abstract
Kinetic regularities of triphenylphosphite ozonide reaction with triphenylphosphite have been studied at T=−75°C to −40°C. The rate of ozonide consumption is estimated as W=k1[(C6H5O)3P·O3]+k2[(C6H5O)3P·O3][(C6H5O)3P], where k1=(2.03±0.39)×10−5s−1(−50°C), 1gk2=(3.82±0.33)−(6.61±0.32)/gq dm3/mol s and θ=2.303RT kcal/mol.
Abstract
В интервале −75°C до −40°C изучены кинетические закономерности реакции озонида трифенилфосфита с трифенилфосфитом. Скорость расходования озонида: W=k1[(C6H5O)3P·O3]+k2[(C6H5O)3P·O3][(C6H5O)3P], где k1=(2,03±0,39)·10−5с−1(−50°C); 1g k2=(3,82±0,33)−(6,61±0,32)/θ л/моль·с, θ=2,303·RT ккал/моль
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Shereshovets, V.V., Korotaeva, N.M., Yanbaev, R.K. et al. Kinetics of triphenylphosphite ozonide consumption in reaction with triphenylphosphite. React Kinet Catal Lett 38, 243–247 (1989). https://doi.org/10.1007/BF02062113
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DOI: https://doi.org/10.1007/BF02062113