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Steady-state rate of complex reactions under limitation and near equilibrium (one-route mechanism of catalytic reactions)

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Abstract

Explicit equations for the steady-state rate in case when one of the steps is rate-limiting, and in the neighborhood of equilibrium have been derived for a one-route mechanism of a catalytic reaction. Equations have been obtained for a dependence of the observed reaction order and activation energy on the thermodynamic characteristics of the overall reaction.

Abstract

Для одномаршрутного механизма каталитической реакции выведены явные выражения для стациорарной скорости в предельных случаях лимитирования одной из стадий механизма реакции и в окрестности равновесия. Получены соотношения, связ⋌вающие наблюдаемый порядок реакции и наблюдаемую энергию активации с термодинамическими характеристиками брутто-реакции.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    M. Z. Lazman & G. S. Yablonskii

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  1. M. Z. Lazman
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  2. G. S. Yablonskii
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Lazman, M.Z., Yablonskii, G.S. Steady-state rate of complex reactions under limitation and near equilibrium (one-route mechanism of catalytic reactions). React Kinet Catal Lett 37, 379–384 (1988). https://doi.org/10.1007/BF02062087

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  • DOI: https://doi.org/10.1007/BF02062087

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