Reaction Kinetics and Catalysis Letters

, Volume 37, Issue 2, pp 349–355 | Cite as

Study of the evolution of a MoO3+Bi2MoO6 mixture in air and in the conditions of mild propene oxidation

  • M. El Jamal
  • M. Forissier
  • G. Coudurier


MoO3 can react with the gamma phase of bismuth molybdate (Bi2MoO6) in the conditions of propene oxidation to form the alpha phase (Bi2Mo3O12) resulting in a more selective catalyst for propene oxidation to acrolein. Intimate contact between MoO3 and the gamma phase is an important factor favoring the formation of the alpha phase.


Oxidation Physical Chemistry Catalysis Propene Bismuth 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


В условиях окисления пропена MoO3 реагирует с γ-фазой молибдата висмута (Bi2MoO6), образуя α-фазу (Bi2Mo3O12), которая представляет собой более селективный катализатор окисления пропена до акролеина.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    K. Aykan: J. Catal.,12, 45 (1968).Google Scholar
  2. 2.
    P. Boutry, R. Montarnal, J. Wrzyszcz: J. Catal.,13, 75 (1969).Google Scholar
  3. 3.
    Ph.A. Batist: J. Chem. Tech. Biotechnol.,29, 451 (1979).Google Scholar
  4. 4.
    I. Matsuura, R. Schuit, K. Hirakawa: J. Catal.,63, 152 (1980).Google Scholar
  5. 5.
    D. Carson, G. Coudurier, M. Forissier, J.C. Vedrine: J. Chem. Soc. Faraday Trans. 1,79, 1921 (1983).Google Scholar
  6. 6.
    L.Y. Erman, E.L. Galperin: Russ. J. Inorg. Chem.,16, 258 (1971);13, 487 (1968).Google Scholar
  7. 7.
    M. Forissier, L. De Mourques, J.L. Portefaix: Rev. Phys. Appl.,11, 639 (1976).Google Scholar
  8. 8.
    O.V. Isaev, O.V. Udalova: Kinet. Katal.,25, 1016 (1984).Google Scholar
  9. 9.
    J.M.D. Tascon, P. Grange, B. Delmon: J. Catal.,97, 287 (1986).Google Scholar

Copyright information

© Akadémiai Kiadó 1988

Authors and Affiliations

  • M. El Jamal
    • 1
  • M. Forissier
    • 1
  • G. Coudurier
    • 1
  1. 1.Institut de Recherches sur la CatalyseCNRSVilleurbanneFrance

Personalised recommendations