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Limitations of evaluation methods for inhibited oxidation of hydrocarbons in the liquid phase. Expressions based on oxygen consumption

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Abstract

Three equations based on oxygen consumption data by which the rate coefficient of the reaction between peroxy radicals and inhibitor molecules can be calculated has been investigated. It was found that these equations do not give acceptable results and that the entire oxygen uptake vs. time curve is necessary for the determination of this rate coefficient.

Abstract

Рассмотрены три уравнения, основанные на данных расхода кислорода и позволяющие определить константы скорости взаимодейс твия пероксидных радикалов с молекулами ингибитора. Найдено, что эти уравнения не дают удовлетворительных результатов и для определения констант скоростей необходимыми являются полные кривые расхода кислорода во времени.

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  1. Central Research Institute for Chemistry of the Hungarian Academy of Sciences, P. O. Box 17, H-1525, Budapest, Hungary

    K. Héberger & J. Lukács

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  1. K. Héberger
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  2. J. Lukács
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Héberger, K., Lukács, J. Limitations of evaluation methods for inhibited oxidation of hydrocarbons in the liquid phase. Expressions based on oxygen consumption. React Kinet Catal Lett 39, 115–122 (1989). https://doi.org/10.1007/BF02061864

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  • DOI: https://doi.org/10.1007/BF02061864

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