Reaction Kinetics and Catalysis Letters

, Volume 39, Issue 1, pp 41–48 | Cite as

Computation in kinetics, II. Simultaneous regression estimation of rate constants and initial concentrations

  • Josef Havel
  • José Luis Gonzalez
  • Maria N. Moreno
Article

Abstract

The general regression program KILET was used for simultaneous estimation of rate constants and initial concentrations. The method can be used either to improve the quality of fit calculating the possible analytical errors of some initial concentrations of a kinetic experiment or for analytical purposes, i.e. for the determination of analytes, while any side reactions can be taken into account.

Keywords

Physical Chemistry Catalysis Analytical Error Side Reaction Analytical Purpose 

Abstract

Общую регрессионную программу KILET использовали для одновременного определения констант скоростей и нача-льных концентраций. Метод может быть использован либо для повышения качества совмещения с расчетами возмож-ных аналитических погрешностей некоторых начальных кон-центраций в кинетических экспериментах, либо для ана-литических целей, а именно для определения аналитов, в то время как все побочные реакции приняты во внимание.

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Copyright information

© Akadémiai Kiadó 1989

Authors and Affiliations

  • Josef Havel
    • 1
  • José Luis Gonzalez
    • 2
  • Maria N. Moreno
    • 2
  1. 1.Department of Analytical Chemistry, College of ScienceJ.E. Purkyne UniversityBrnoCzechoslovakia
  2. 2.Department of Physical Chemistry, Faculty of ChemistrySalamanca UniversitySalamancaSpain

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