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Recent data on the kinetics of ethylene chlorination

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Abstract

Chlorination of ethylene with chlorine in C2H4Cl2 solvent, with and without FeCl3 catalyst, was studied in the temperature range from 293 to 308 K. Simultaneous addition and substitution were detected. The rate constants were determined by numerical integration of kinetic equations. Activation energies and preexponential factors were calculated as well.

Abstract

Хлорирование этилена хлорором в дихлорэтане на катализаторе FeCl3 или без него исследовали в интервале температур от 293 до 308 К. Детектировали одновременное присоединение и замещение. Константы скорости определяли числовым интегрованием кинетических уравнений. Также были рассчитаны энергии активации и предэкспоненциальные множители.

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  1. Research Laboratory for Inorganic Chemistry of the Hungarian Academy of Sciences, Budaőrsi ut 45, H-1112, Budapest

    János Szépvölgyi

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  1. János Szépvölgyi
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Szépvölgyi, J. Recent data on the kinetics of ethylene chlorination. React Kinet Catal Lett 39, 15–20 (1989). https://doi.org/10.1007/BF02061849

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  • DOI: https://doi.org/10.1007/BF02061849

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