Abstract
The six-step Boreskov reaction mechanism gives a good explanation of recent Cs/V catalyst kinetic data. The high pressures of oxygen and sulfur trioxide during reaction were shown to cause a low activation energy between 360–400°C for the Cs/V catalyst.
Abstract
Шестиступенчатый механизм реакции, предложенный Боресковым, хорошо объясняет новейшие кинетические данные катализатора Cs/V. Высокое давление кислорода и трехокиси серы в ходе реакции приводят к ниаким энергиям активации в интервале температур 360–400°C, для катализатора Cs/V.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. Urbanek, M. Trela: Catal. Rev.-Sci. Engng.,21, 73 (1980)
J.R. Donovan, R.D. Stolk, M.L. Unland: Applied Industrial Catalysis, Vol. 2, page 245. Academic Press, New York 1983.
F.J. Doering, H.K. Yuen, P.A. Berger, M.L. Unland: J. Catal.104, 186 (1987)
B.S. Balzhinimaev, V.E. Ponomarev, N.P. Belyaeva, A.A. Ivanov, G.K. Boreskov: React. Kinet. Catal. Lett.,30, 23 (1986)
P. Mars, J.G.H. Maessen: J. Catal.,10 (1968)
G.K. Boreskov, A.A. Ivanov, B.S. Balzhinimaev, L.M. Karatovskaya: React. Kinet. Catal. Lett.,14, 25 (1968)
G.K. Boreskov, R.A. Buyanov, A.A. Ivanov: Kinet. Katal.,8, 153 (1967)
V.A. Chumachenko, B.S. Balzhinimaev, L.M. Karnatovskaya, Yu.Sh. Matros, A.I. Oruzheinikov: React. Kinet. Catal. Lett.,20, 145 (1982)
F.J. Doering, M.L. Unland, D.A. Berkel: Chem. Engng. Sci.,43, 221 (1988)
A.A. Ivanov, B.S. Balzhinimaev: React. Kinet. Catal. Lett.,35, 143 (1987)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Doering, F.J. A mechanistic explanation for the SO2 oxidation rate data of a Cs/V catalyst at high pressures and conversions. React Kinet Catal Lett 39, 1–6 (1989). https://doi.org/10.1007/BF02061847
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02061847