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Reaction Kinetics and Catalysis Letters

, Volume 7, Issue 2, pp 219–224 | Cite as

Catalytic properties of sodium-containing silica gel in n-heptane decomposition

  • S. Malinowski
  • T. Woźniewski
  • E. Fedoryńska
Article
  • 19 Downloads

Abstract

n-Heptane decomposition reactions on silica catalysts containing various amounts of sodium ions were studied. Ethylene, methane and propylene as well as unbrached α-olefins were the main reaction products. The comparison of the experimental and theoretical results suggests a free-radical reaction mechanism.

Keywords

Sodium Ethylene Physical Chemistry Methane Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Были исследованы реакции разложения н-гептана на катализаторе двуокиси кремния, содержащем различные количества ионов натрия. Основными продуктами были этилен, метан и пропилен, а также неразветвленные α-олефины. Сравнение экспериментальных данных с теоретическими указывает на свободно-радикальный механизм реакции.

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Copyright information

© Akadémiai Kiadó 1977

Authors and Affiliations

  • S. Malinowski
    • 1
  • T. Woźniewski
    • 1
  • E. Fedoryńska
    • 1
  1. 1.Institute of Organic Chemistry and TechnologyTechnical University (Politechnika)WarsawPoland

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