Skip to main content
SpringerLink
Log in

A rhodium-DIOP complex attached to an inorganic support as catalyst for enantioselective syntheses

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

A rhodium-DIOP complex attached to a macroporous silica gel has been tested as catalyst for the enantioselective hydrosilylation of acetophenone and hydrogenation of α-acetamidocinnamic acid. The catalyst has been found to be comparable in asymmetric efficiency to homogeneous analogues. In both reactions, the activity of the heterogenized catalyst was by ca. one order of magnitude lower relative to the homogeneous system.

Abstract

Каталитические свойства комплекса родия с DIOP, связанного на макропористом силикагеле, были проверены в энантиоселективном гидросилилировании ацетофчнона и гидрировании α-ацетамидокоричной кислоты. Было найдено, что катализатор по своей асимметричной эффективности сравним с гомогенными аналогами. В обоих реакциях активность гетерогенного катализатора была приблизительно на один порядок ниже по сравнению с гомогенными системами.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Part XLIX: in Catalysis by Metal Complexes; Part XLVIII: J. Mol. Catal. (in press).

  2. A. Dumont, J. C. Poulin, T. P. Dang, H. B. Kagan: J. Amer. Chem. Soc.,95, 8295 (1973).

    Google Scholar 

  3. G. Strukui, M. Bonivento, M. Graziani, E. cernia, N. Palladino: Inorg. Chim. Acta,12, 15 (1975).

    Google Scholar 

  4. N. Takaishi, H. Imai, C. A. Bartelo, J. K. Stille: J. Amer. Chem. Soc.,98, 5400 (1976).

    Google Scholar 

  5. J. Beneš, J. Hetflejš: 6th Internat. Congr. on Catalysis, Paper B 42, London 1976.

  6. J. Beneš, J. Hetflejš: Collect. Czech. Chem. Commun.,41, 2264 (1976).

    Google Scholar 

  7. J. Vilím, J. Hetflejš: Collect. Czech. Chem. Commun. (in press).

  8. J. Vilím, J. Hetflejš: Chem. Prumysl (in press).

  9. J. Beneš, J. Hetflejš: Collect. Czech. Chem. Commun.,41, 2254 (1976).

    Google Scholar 

  10. M. Čapka: Synth. React. Metal-Org. Chem. (in press).

  11. M. Černý: Collect. Czech. Chem. Commun. (in press).

  12. L. Porri, A. Lionetti, A. Imizi: Chem. Commun., 336 (1965).

  13. H. B. Kagan, T. P. Dang: J. Amer. Chem. Soc.,94, 6429 (1976).

    Google Scholar 

  14. J. Vilím, J. Hetflejš: Chem. Listy,70, 188 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02, Prague 6-Suchdol, Czechoslovakia

    I. Kolb, M. Černý & J. Hetflejš

Authors
  1. I. Kolb
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Černý
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Hetflejš
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Parts XLIX and XLVIII, cf. Ref. /1/

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kolb, I., Černý, M. & Hetflejš, J. A rhodium-DIOP complex attached to an inorganic support as catalyst for enantioselective syntheses. React Kinet Catal Lett 7, 199–204 (1977). https://doi.org/10.1007/BF02061839

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02061839

Keywords

Search

Navigation