Abstract
The γ-radiolysis of IO −4 in aqueous solution and binary solutions containing iso-propanol has been studied as a function of reactant concentration and absorbed dose. The disappearance of periodate ion in the presence of alcohol is found to be higher as compared to that observed in the pure system. The trend in the G-values determined at various combinations of the reactant concentrations suggests the occurrence of a chain reaction in the radiolytic process.
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H. J. ARNIKAR, S. F. PATIL, A. A. BODHE, R. D. POKHARKAR, Radiochem. Radioanal. Lett., 23 (1975) 307.
H. J. ARNIKAR, S. F. PATIL, B. S. M. RAO, A. A. BODHE, R. D. POKHARKAR, Radiochim. Acta., 23 (1976) 109.
H. J. ARNIKAR, S. F. PATIL, B. S. M. RAO, R. D. POKHARKAR, Radiochem. Radioanal. Lett., 35 (1978) 1.
H. J. ARNIKAR, S. F. PATIL, B. S. M. RAO, M. J. BEDEKAR, Radiochem. Radioanal. Lett., 28 (1977) 337.
H. J. ARNIKAR, B. S. M. RAO, M. J. BEDEKAR, Radiochem. Radioanal. Lett., 35 (1978) 39.
G. N. GAIKWAD, Ph. D. Thesis, University of Poona, 1985.
W. L. LOCKHART, M. M. JONES, J. Inorg. Nucl. Chem., 28 (1966) 2619.
F. BARAT, L. GILLES, B. HICKEL, B. LESIGNE, J. Phys. Chem., 75 (1971) 2177.
N. HASSAN, C. HEITZ, J. Chim. Phys., 71 (1974) 127.
S. N. BHATTACHARYA, D. K. BARDHAN, Bull. Chem. Soc. Japan, 43 (1970) 2808.
M. ANBAR, M. BAMBENEK, A. B. ROSS, NSRDS-NBS, Vol. 43, 1973, U. S. Dept. of Commerce, National Bureau of Standards, Washington, D.C.
A. B. ROSS, Supplement to NSRDS-NBS, Vol. 43, 1975, U. S. Dept. of Commerce, National Bureau of Standards, Washington, D. C.
M. ANBAR, P. NETA, Int. J. Appl. Radiation Isotopes, 18 (1967) 493.
M. ANBAR, FARHATAZIZ, A. B. ROSS, NSRDS-NBS, Vol. 51, 1975, U. S. Dept. of Commerce, National Bureau of Standards, Washington, D. C.
R. D. POKHARKAR, Ph. D. Thesis, University of Poona, 1979.
S. K. PATNAIK, H. J. ARNIKAR, M. R. SARKHAWAS, Ind. J. Chem., 19A (1980) 945.
L. M. DORFMAN, G. E. ADAMS, Reactivity of Hydroxyl Radical in Aqueous Solutions, NSRDS-NBS, Vol. 46, 1973, U. S. Dept. of Commerce, National Bureau of Standards, Washington, D. C.
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Patil, S.F., Patil, R.M. & Mudaliar, M. Effect of iso-propanol on the radiolysis of aqueous solutions of periodate. Journal of Radioanalytical and Nuclear Chemistry, Articles 139, 323–329 (1990). https://doi.org/10.1007/BF02061818
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DOI: https://doi.org/10.1007/BF02061818