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Physico-chemical studies on the complexes of actinides with fluorinated β-diketones and neutral oxodonors

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Abstract

Several adducts of U(IV) and Th(IV) with 1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedione (FOD) as β-diketone and a variety of neutral oxodonors were synthesized and characterized by visible spectral, proton magnetic resonance as well as thermogravimetric studies. Adducts with dimethylformamide (DMF) were found to be most volatile, whereas with trioctylphosphine oxide (TOPO) were quite susceptible towards decomposition.

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Author notes

  1. G. A. Rama Rao

    Present address: Fuel Chemistry Divison, B. A. R. C., 400085, Bombay, India

  2. W. D. Lloyd

    Present address: Department of Chemistry, UTEP, 79968-0513, El-Paso, Texas, USA

Authors and Affiliations

  1. Radiochemistry Division, B. A. R. C., 400085, Bombay, (India)

    V. K. Manchanda, G. A. Rama Rao & W. D. Lloyd

Authors
  1. V. K. Manchanda
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  2. G. A. Rama Rao
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  3. W. D. Lloyd
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Manchanda, V.K., Rama Rao, G.A. & Lloyd, W.D. Physico-chemical studies on the complexes of actinides with fluorinated β-diketones and neutral oxodonors. Journal of Radioanalytical and Nuclear Chemistry, Articles 139, 223–229 (1990). https://doi.org/10.1007/BF02061806

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  • DOI: https://doi.org/10.1007/BF02061806

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