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Mechanism of catalysis and factors responsible for oxide catalyst activity in deep oxidation reactions

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Abstract

A general scheme for the deep oxidation mechanism on oxide catalysts including stepwise and concerted mechanisms as well as their mutual transformations is suggested. The principal factor responsible for the activity in the concerted mechanism region is the rate of oxygen binding. For the stepwise mechanism the main factor is the rate of catalyst interaction with oxidizable reactant.

Abstract

Предложена общая схема механизма реакций глубокго окисления на оксидных катализиторах, включающая стадийный и слитный механизм и переходы между ними. Главным фактором определяющим активность в областн слитного механизма, является скорость связывания кислорода. В области стадийного механизма главным фактором является скорость взаимодействия с катализатором окисляемого реагента.

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References

  1. G. K. Boreskov: Heterogeneous Catalysis, Nauka, Moskva 1986.

    Google Scholar 

  2. G. I. Golodets: Heterogeneous Catalytic Reactions. Naukova Dumka, Kiev 1977.

    Google Scholar 

  3. V. V. Popovskii: Kinet. Katal.,13, 1190 (1972).

    Google Scholar 

  4. G. K. Boreskov, V. D. Sokolovskii: Izv. Akad. Nauk SSSR, ser. khim.,4, 46 (1976).

    Google Scholar 

  5. A. G. Anshits, V. D. Sokolovskii, G. K. Boreskov, A. A. Davydov: Dokl. Akad. Nauk SSSR,213, 607 (1973).

    Google Scholar 

  6. G. K. Boreskov, V. I. Marshneva, V. D. Sokolovskii: Dokl. Akad. Nauk SSSR,199, 1091 (1971).

    Google Scholar 

  7. V. D. Sokolovskii: React. Kinet. Catal. Lett.,35, 337 (1987).

    Google Scholar 

  8. V. I. Marshneva, G. K. Boreskov, V. D. Sokolovskii: Proc. 1st Soviet-Japanese Seminar on Catalysis, Preprint No 25, Inst. Katal., Novosibirsk 1971.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    V. D. Sokolovskii

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  1. V. D. Sokolovskii
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Sokolovskii, V.D. Mechanism of catalysis and factors responsible for oxide catalyst activity in deep oxidation reactions. React Kinet Catal Lett 37, 121–126 (1988). https://doi.org/10.1007/BF02061720

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  • DOI: https://doi.org/10.1007/BF02061720

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