Hyperfine Interactions

, Volume 28, Issue 1–4, pp 789–792 | Cite as

Application of Mössbauer spectroscopy to the studies of FeCl3, SnCl4 and SbCl5 doped polypyrrole

  • Z. Kucharski
  • C. Budrowski
  • A. Proń
  • G. Dehe
  • J. Suwalski
Electronic Structure, Chemistry

Abstract

Chemically polymerized polypyrrole was chemically doped with FeCl3, SnCl4, and SbCl5. In57Fe and119Sn ME studies, samples prepared under rigorously anhydrous conditions show only one type of iron and tin with Mössbauer parameters characteristic of FeCl 4 and SnCl5 whereas in121Sb experiments two types of antimony corresponding to SbCl3 and SbCl 6 have been detected.From the temperature dependence of the recoil free fraction the Mössbauer lattice temperatures were estimated as 125 K and 105 K for polypyrrole doped with iron chloride and with tin chloride respectively.

Keywords

Iron Spectroscopy Chloride Thin Film Antimony 

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Copyright information

© J.C. Baltzer A.G., Scientific Publishing Company 1986

Authors and Affiliations

  • Z. Kucharski
    • 1
  • C. Budrowski
    • 2
  • A. Proń
    • 3
  • G. Dehe
    • 4
  • J. Suwalski
    • 1
  1. 1.Institute of Atomic EnergySwierk, OtwockPoland
  2. 2.Institute of Inorganic TechnologyTechnical University of WarsawWarszawa, Noakowskiego 3Poland
  3. 3.Institute for Polymer Research and TechnologyTechnical University of WarsawWarszawa, Noakowskiego 3Poland
  4. 4.Institute of PhysicsUniversity of LeipzigLinnestrasse 5GDR

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