Abstract
Dinitrogen reduction on a mercury cathode has been studied in an alkaline methanol solution with guanidine buffer (pK=13.6) in the presence of homogeneous catalysts (alkoxy complexes of Mo(III) and Ti(III). As is found, dinitrogen electroreduction occurs on the electrode surface. The reaction rate is determined by the rate of electron transfer.
Abstract
Исслдовано восстановление азота на ртутном катоде в гуанидиновом буферном (pK=13,6) метанольном щелочном расе в присутствии гомогеннЫх катализаторпб-метилатов Ti(III) т Mo(III). Показано, что злектрртановление азота происходит на поверхности злекрда. Скорость определяющей стадией является перенос ялектрона.
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Kulakovskaya, S.I., Vasilieva, L.P. & Efimov, O.N. Electroreduction of dinitrogen in a Ti(III)−Mo(III)-guanidine system. React Kinet Catal Lett 14, 181–186 (1980). https://doi.org/10.1007/BF02061284
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DOI: https://doi.org/10.1007/BF02061284