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A method to study reaction kinetics over finely-dispersed catalysts in stationary and non-stationary conditions

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Abstract

The application of a small-volume gradientless flow reactor with a vibrofluidized catalyst bed, mass-spectrometric analysis of the reaction products and a membrane turbulizer for alternate purging of the reactor filters by the reaction mixture permits to study the kinetics of complex catalytic reactions over catalysts with 50–100μm grains in both stationary and nonstationary conditions.

Abstract

Использование безградиентного проточного реактора малого объема с виброожиженным слоем катализатора, масс-спектрометрического метода анализа продуктов реакции и мембранного турбулизатора для попеременного отдува реакционной смесью фильтров реактора позволяет исследовать кинетику сложных каталитических реакций на катализаторах с размерами частиц 50–100 микрон в стационарных и нестационарных условиях.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    G. G. Isaeva, V. I. Timoshenko & M. G. Slinko

Authors
  1. G. G. Isaeva
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  2. V. I. Timoshenko
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  3. M. G. Slinko
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Isaeva, G.G., Timoshenko, V.I. & Slinko, M.G. A method to study reaction kinetics over finely-dispersed catalysts in stationary and non-stationary conditions. React Kinet Catal Lett 14, 43–48 (1980). https://doi.org/10.1007/BF02061262

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  • DOI: https://doi.org/10.1007/BF02061262

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