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Characterization of strong complexing agents in natural waters by liquid-liquid extraction

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Abstract

The solvent extraction method for characterization of strong complexing agents in natural waters has been developed. The titration curve the relationship between the concentration of a metal added in a sample solution and that of the metal in the organic phase after extraction, has been modelled on the basis of Ringbom's theory. The concentration of the metal in the organic phase is easily calibrated by the activities of the radioisotopic spike. The conditional stability products for complexation of natural ligands with cobalt (57Co), manganese (54Mn) and zinc (65Zn) were calculated from the titration curves.

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References

  1. M. PLAVSIC, D. KRZNARIC, M. BRANICA, Marine Chem., 11 (1982) 17.

    Google Scholar 

  2. H. BLUYSTEIN, R. F. SHAW, Environ. Sci. Tech., 15 (1981) 1100.

    Google Scholar 

  3. M. S. SHUMAN, G. P. WOODWARD, Jr, Anal. Chem., 45 (1973) 2032.

    Google Scholar 

  4. D. K. RYAN, J. H. WEBER, Anal. Chem., 54 (1982) 986.

    Google Scholar 

  5. R. T. TRITT, J. H. WEBER, Environ. Sci. Tech., 15 (1981) 1204.

    Google Scholar 

  6. P. G. C. CAMPBELL, M. BISSON, R. GAGNE, A. TESSIER, Anal. Chem., 49 (1977) 2358.

    Google Scholar 

  7. M. L. CROSSER, H. E. ALLEN, Soil. Sci., 123 (1977) 176.

    Google Scholar 

  8. R. G. SMITH, Jr., Anal. Chem., 48 (1976) 74.

    Google Scholar 

  9. P. A. GILLESPIRE, R. F. VACCARO, Limnolo. Oceano., 23 (1978) 543.

    Google Scholar 

  10. T. D. WALTE, M. M. MOREL, Anal. Chem., 55 (1983) 1268.

    Google Scholar 

  11. Y. SASAKI, Bunseki Kagaku, 27 (1978) 386.

    Google Scholar 

  12. K. IWASE, K. KOBAYASHI, H. HAMAGUCHI, K. FUWA, Nippon Kagaku Zasshi, (1983), 169.

  13. J. BUFFLE, F. L. GRETER, W. HAERDI, Anal. Chem., 49 (1977) 216.

    PubMed  Google Scholar 

  14. C. M. G. VAN DEN BERG, J. F. KRAMER, in: Chemical Modeling in Aqueous Systems, E. A. JENNE (Ed.), A. C. S., Washington, 1979.

    Google Scholar 

  15. K. W. HANCK, J. W. DILLARD, Anal. Chem., 49 (1977) 404.

    PubMed  Google Scholar 

  16. R. J. STOLZBERG, D. ROSIN, Anal. Chem., 49 (1977) 226.

    Google Scholar 

  17. A. J. RINGBOM, Complexation in Analytical Chemistry, Interscience, New York, 1963.

    Google Scholar 

  18. R. M. SMITH, A. E. MARTELL, Critical Stability Constants, Plenum Press, New York, 1977.

    Google Scholar 

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Authors and Affiliations

  1. Radioisotope Center, Kyushu University 16, Hakozaki, Higashi-ku, 812, Fukuoka, Japan

    S. Osaki

  2. Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, 812, Fukuoka, Japan

    N. Mannen & Y. Takashima

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  1. S. Osaki
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  2. N. Mannen
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  3. Y. Takashima
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Osaki, S., Mannen, N. & Takashima, Y. Characterization of strong complexing agents in natural waters by liquid-liquid extraction. Journal of Radioanalytical and Nuclear Chemistry, Articles 99, 219–229 (1986). https://doi.org/10.1007/BF02060842

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  • DOI: https://doi.org/10.1007/BF02060842

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