Labelling of long chain fatty acids by non isotopic nucleophilic halogen exchange

  • E. Hallaba
  • A. A. Al-Suhybani
  • F. S. Zaki
Article
  • 30 Downloads

Abstract

The parameters of two exchange methods of preparing pure 97% labelled 17-Br-HDA in acetone and in benzene with dry NaI* in a closed system are described. In aprotic solvents the need for a phase transfer catalyst up to 50μg is necessary to dissolve the dry NaI*. The use of aqueous medium in the exchange is totally prohibited. Energies of activation are calculated for both reactions.

Keywords

Physical Chemistry Acetone Benzene Inorganic Chemistry Aqueous Medium 

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Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • E. Hallaba
    • 1
  • A. A. Al-Suhybani
    • 1
  • F. S. Zaki
    • 1
  1. 1.Chemistry Department, College of ScienceKing Saud UniversityRiyadh

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