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Studies on the adsorption behaviour of trace amounts of cerium on manganese dioxide from aqueous solutions in the presence of complexing agents

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Abstract

Adsorption behaviour of trace amounts of cerium on manganese dioxide has been studied as a function of pH (1–10) in the presence of EDTA, oxalate, citrate, tartrate, cyanide and thiocyanate ions. The influence of their concentration on the adsorption has also been investigated. Maximum adsorption of cerium has been noticed at pH≥6. Under specific conditions, adsorption of other metal ions has been measured for comparison. Low distribution coefficients are obtained for Cs(I) and Hg(II) in the presence of oxalate, and for Cr(III) in the presence of thiocyanate ions. Based on these data, separation of cesium, chromium and mercury from rare earths and cerium scavenging in natural water or in waste water treatment can be achieved.

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  1. Nuclear Chemistry Division, Pakistan Institute of Nuclear Science and Technology, P.O.Nilore, Islamabad, Pakistan

    S. M. Hasany & M. H. Chaudhary

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  1. S. M. Hasany
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  2. M. H. Chaudhary
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Hasany, S.M., Chaudhary, M.H. Studies on the adsorption behaviour of trace amounts of cerium on manganese dioxide from aqueous solutions in the presence of complexing agents. Journal of Radioanalytical and Nuclear Chemistry, Articles 111, 199–210 (1987). https://doi.org/10.1007/BF02060535

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