Skip to main content
SpringerLink
Log in

Mössbauer spectroscopic and X-ray diffraction study of the thermal decomposition of natural siderite and goethite

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Thermal decomposition of natural siderite and goethite has been studied using Mössbauer spectroscopy and X-ray diffraction. Hematite and magnetite were the principal compounds formed during high temperature treatment of siderite. Natural goethite transformed to hematite at high temperatures. The crystal structures, stoichiometry and the nuclear magnetic properties of Fe-oxides formed are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. MUSIĆ Z. DRAGČEVIĆ O. LAHODNY-ŠARC, I. NAGY-CZAKÓ, A. VÉRTES, J. Physique, 41 (1980) C1–305.

    Google Scholar 

  2. S. MUSIĆ, I. NAGY-CZAKÓ, A. VÉRTES, O. HADŽIJA, Bull. Soc. Chim. (Beograd), 45 (1980) 541.

    Google Scholar 

  3. I. NAGY-CZAKÓ, S. MUSIĆ, A. VÉRTES, O. HADŽIJA, Z. DRAGČEVIĆ, O. LAHODNYŠARC, Acta Geol. Hung., 24 (1981) 149.

    Google Scholar 

  4. S. MUSIĆ, H. LEIDHEISER, JR., G. W. SIMMONS, Bull. Soc. Chim. (Beograd), 46 (1981) 571.

    Google Scholar 

  5. G. W. SIMMONS, H. LEIDHEISER, Jr., Corrosion and Interfacial Reaction, in: Application of Mössbauer Spectroscopy, Vol. 1, Bell Telephone Laboratories, Inc. 1976, p. 85.

  6. T. MEISEL, Kém. Közlem., 48 (1977) 41.

    Google Scholar 

  7. L. H. BOWEN, Mössbauer Spectroscopy of Ferric Oxides and Hydroxides, in: Mössbauer Effect Data Index-1979, Plenum, New York 1979, p. 76.

    Google Scholar 

  8. F. J. BERRY, Trans. Met. Chem., 4 (1979) 209.

    Google Scholar 

  9. Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Powder Diffraction File, Swarthmore, Pa., USA

  10. S. MUSIĆ, I. CZAKÓ-NAGY, S. POPOVIĆ, A. VÉRTES, M. TONKOVIĆ, Croat. Chem. Acta, 59 (1968) 833.

    Google Scholar 

  11. Structure Reports, 22 (1957) 298; 23 (1958) 329; 24 (1959) 315; 33A (1968) 267; International Union of Crystallography, D. Reidel Publ. Co., Dordrecht, Holland.

  12. A. F. WELLS, Structural Inorganic Chemistry, 4th ed. Claredon Press, Oxford, 1975.

    Google Scholar 

  13. L. BAUMANN, Introduction to Ore Deposits, John Wiley and Sons, Inc. New York 1976, p. 40.

    Google Scholar 

  14. V. I. GOLDANSKII, E. F. MAKAROV, I. P. SUZDALEV, I. A. VINOGRADOV, Phys. Rev. Letters, 20 (1968) 137.

    Google Scholar 

  15. R. M. HOUSLEY, U. GONSER, R. W. GRANT, Phys. Rev. Letters, 20 (1968) 1279.

    Google Scholar 

  16. V. I. GOLDANSKII, E. F. MAKAROV, I. P. SUZDALEV, I. A. VINOGRADOV, Zh. Eksp. Teor. Fiz., 58 (1970) 760.

    Google Scholar 

  17. I. A. VINOGRADOV, A. M. PRITCHARD, E. F. MAKAROV, I. P. SUZDALEV, Sol. State Commun., 8 (1970) 965.

    Google Scholar 

  18. I. DÉZSI, K. KULCSÁR, D. L. NAGY, L. PÓCS, Proc. Conf. Appl. Mössbauer Effect—Tihany 1969, Akadémiai Kiadó, Budapest 1971, p. 247.

    Google Scholar 

  19. H. D. PFANNES, U. GONSER, Appl. Phys., 1 (1973) 93.

    Google Scholar 

  20. D. L. NAGY, K. KULCSAR, H. SPIERING, R. ZIMMERMANN, J. Physique, 35 (1974) C6–385.

    Google Scholar 

  21. A. M. PRITCHARD, J. R. HADDON, G. N. WALTON, Corrosion Sci. 11 (1971) 11.

    Google Scholar 

  22. C. GLEITZER, J. B. GOODENOUGH, Mixed-Valence Iron Oxides in: Structure and Bonding, No 61., Springer-Verlag, Berlin-Heidelberg 1985, p. 1.

    Google Scholar 

  23. A. GOVAERT, C. DAUWE, P. PLINKE, E. DE GRAVE, J. DE SITTER, J. Physique, 37 (1976) C6–825.

    Google Scholar 

  24. K. C. SHARMA, J. L. DORMANN, T. K. VIEN, J. P. EYMERY, IEEE Trans Magn. MAG-17 (1981) 2721.

    Google Scholar 

  25. J. H. JOHNSTON, K. NORRISH, Aust. J. Soil Res., 19 (1981) 231.

    Google Scholar 

  26. S. A. FYSH, J. OSTWALD, Miner. Magazine, 47 (1983) 209.

    Google Scholar 

  27. E. MURAD, Miner. Magazine, 43 (1979) 355.

    Google Scholar 

  28. J. G. FORSYTH, I. G. HEDLEY, C. E. JOHNSON, J. Phys. C., 1 (1968) 179.

    Google Scholar 

  29. A. M. VAN DER KRAAN, Ph. D. Thesis, Technical High School, Delft 1972.

  30. U. SCHWERTMANN, P. CAMBIER, E. MURAD, Clays Clay Minerals, 33 (1985) 369.

    Google Scholar 

  31. E. MURAD, U. SCHWERTMANN, Clay Minerals, 18 (1983) 301.

    Google Scholar 

  32. E. DE GRAVE, L. H. BOWEN, G. G. ROBBRECHT, Proc. 2nd European Conf., Veldhoven, The Netherlands 7–9 June 1982, R. METSELAAR et al., (Ed.), Studies in Inorganic Chemistry, Vol 3., Elsevier, Amsterdam, 1983, p. 571.

    Google Scholar 

  33. E. DE GRAVE, D. CHAMBAERE, L. H. BOWEN, J. Mag. Magn. Mat., 30 (1983) 349.

    Google Scholar 

  34. E. MURAD, Phys. Letters, 111A (1985) 79.

    Google Scholar 

  35. R. E. VANDENGERGHE, A. E. VERBEECK, E. DE GRAVE, W. STIERS, Hyperfine Interact. 29 (1986) 1157.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Rudjer Bošković Institute, P.O. Box 1016, 41001, Zagreb, Yugoslavia

    S. Musić & S. Popović

Authors
  1. S. Musić
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Popović
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Musić, S., Popović, S. Mössbauer spectroscopic and X-ray diffraction study of the thermal decomposition of natural siderite and goethite. Journal of Radioanalytical and Nuclear Chemistry, Articles 111, 27–41 (1987). https://doi.org/10.1007/BF02060518

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02060518

Keywords

Search

Navigation