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Deuteriation of 4-methylbenzoic acid in the presence of a homogeneous potassium tetrachloroplatinate(II) catalyst

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Abstract

The kinetics of deuteration of 4-methylbenzoic acid in the presence of a homogenous K2PtCl4 in a medium containing 50% solution of deuteriated acetic acid in heavy water has been studied at 130°C. The quasiunimolecular H/D rate constants for the methyl group, the ortho and meta aromatic ring hydrogens were determined by NMR.

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Authors and Affiliations

  1. Department of Chemistry, Warsaw University, ul. Pasteur 1, 02-093, Warsaw, Poland

    M. Kańska & R. Kański

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  1. M. Kańska
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  2. R. Kański
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Kańska, M., Kański, R. Deuteriation of 4-methylbenzoic acid in the presence of a homogeneous potassium tetrachloroplatinate(II) catalyst. Journal of Radioanalytical and Nuclear Chemistry Articles 210, 35–43 (1996). https://doi.org/10.1007/BF02055404

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  • DOI: https://doi.org/10.1007/BF02055404

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