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Extraction chromatography in the DHDECMP—HNO3 system

I. Extraction behaviour of Ce(III) and Am(III) with the DHDECMP/XAD-4 resin

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Abstract

The extraction behaviour of Ce(III) and Am(III) in extraction chromatography has been investigated on the basis of partition and infrared studies. The stationary phase was purified undiluted DHDECMP supported on Amberlite XAD-4 and the mobile phase was nitric acid. The results have shown that the equilibria for the extraction of Ce(III) and Am(III) by the DHDECMP/XAD-4 resin agreed very closely with those in solvent extraction.

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References

  1. W. W. SCHULZ, L. D. McISAAC, Report ARH-SA-263, 1977.

  2. L. D. McISAAC,J. D. BAKER, J. F. KRUPA, R. E. LAPOINTE, D. H. MEIKRANTZ, N. C. SCHROEDER, Report ICP-1180, 1979.

  3. L. L. MARTELLA, J. D. NAVRATIL, Report RFP-2812, 1979.

  4. R. R. SHOUN, W. J. McDOWELL, Radiochim. Acta, 29 (1981) 143.

    Google Scholar 

  5. E. P. HORWITZ, D. G. KALINA, A. C. MUSCATELLO, Separ. Sci. Technol., 16 (1981) 403.

    Google Scholar 

  6. E. P. HORWITZ, A. C. MUSCATELLO, D. G. KALINA, L. KAPLAN, Separ. Sci. Technol., 16, (1981) 417.

    Google Scholar 

  7. D. G. KALINA, E. P. HORWITZ, L. KAPLAN, A. C. MUSCATELLO, Separ. Sci. Technol., 16 (1981) 1127.

    Google Scholar 

  8. E. P. HORWITZ, H. DIAMOND, D. G. KALINA, Plutonium Chemistry, ACS Symposium Series No. 216, W. C. CARNALL, G. R. CHOPPIN (Eds), American Chemical Society, Washington, D. C., 1983, Chap. 27, p. 433.

    Google Scholar 

  9. G. F. VANDEGRIFT, R. A. LEONARD, M. J. STEINDLER, E. P. HORWITZ, L. J. BASILE, H. DIAMOND, D. G. KALINA, L. KAPLAN, Report ANL-84-45, 1984.

  10. Z. HUGEN, Y. YUXING, Y. XUEXIAN, L. ZHANGJI, Inorg. Chim. Acta, 94 (1984) 189.

    Google Scholar 

  11. E. P. HORWITZ, K. A. MARTIN, H. DIAMOND, L. KAPLAN, Solvent Extr. Ion Exch., 4 (1986) 449.

    Google Scholar 

  12. J. AKATSU, T. KIMURA, J. Radioanal. Nucl. Chem., 140 (1990) 199.

    Google Scholar 

  13. G. R. CHOPPIN, W. F. STRAZIK, Inorg. Chem., 4 (1965) 1250.

    Google Scholar 

  14. T. W. MARTIN, R. W. GLASS, J. Am. Chem. Soc., 92 (1970) 5075.

    Google Scholar 

  15. B. M. L. BANSAL, S. K. PATIL, H. D. SHARMA, J. Inorg. Nucl. Chem., 26 (1964) 993.

    Google Scholar 

  16. K. A. MARTIN, E. P. HORWITZ, J. R. FELLARO, Solvent Extr. Ion Exch., 4 (1986) 1149.

    Google Scholar 

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Kimura, T., Akatsu, J. Extraction chromatography in the DHDECMP—HNO3 system. Journal of Radioanalytical and Nuclear Chemistry, Articles 149, 13–23 (1991). https://doi.org/10.1007/BF02053708

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  • DOI: https://doi.org/10.1007/BF02053708

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