Abstract
The structure of the higher oxide of technetium in various states is discussed. The results allow to regard the three-phase state as coordination tetrahedra TcO4 and coordination octahedra TcO3 bonded through Tc−O−Tc bridges and to consider the gas-phase and liquid-state as coordination tetrahedra and their dimeric forms.
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Sinyakova, G.S. Technetium(VII): Analysis of the possible structure of the higher oxide in various states. Journal of Radioanalytical and Nuclear Chemistry, Articles 158, 261–271 (1992). https://doi.org/10.1007/BF02047113
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DOI: https://doi.org/10.1007/BF02047113