Skip to main content
Log in

Technetium(VII): Analysis of the possible structure of the higher oxide in various states

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The structure of the higher oxide of technetium in various states is discussed. The results allow to regard the three-phase state as coordination tetrahedra TcO4 and coordination octahedra TcO3 bonded through Tc−O−Tc bridges and to consider the gas-phase and liquid-state as coordination tetrahedra and their dimeric forms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. COLTON, R. PEACOCK, Quart. Rev. Chem. Soc., 4 (1962) 299.

    Google Scholar 

  2. G. E. BOYD, J. Chem. Educ., 36 (1959) 3.

    Google Scholar 

  3. S. FRIED, A. H. JAFFEY, N. F. HALL, L. E. GLENDEMIN, Phys. Rev., 81 (1951) 751.

    Google Scholar 

  4. G. E. BOYD, I. W. COBBLE, C. M. NELSON, W. T. SMITH, J. Am. Chem. Soc., 74 (1952) 551.

    Google Scholar 

  5. C. R. RULF, R. A. PACER, R. F. HIRSCH, J. Inorg. Nucl. Chem., 29 (1967) 681.

    Google Scholar 

  6. A. N. MURIN, V. D. NYEFEDOV, YU A. RYUKHIN, M. N. TOROPOVA, Usp. Khim., 30 (1961) 274.

    Google Scholar 

  7. V. I. SPITSIN, A. F. KUZINA, Usp. Khim., 46 (1979) 178.

    Google Scholar 

  8. A. F. KUZINA, Radiochemistry, 2 (1979) 178.

    Google Scholar 

  9. V. M. SPITSIN, A. F. KUZINA, Technetiun, Nauka, Moscow, 1981, (in Russian).

    Google Scholar 

  10. L. L. ZAITSEVA, A. V. VELICHKO, I. V. VINOGRADOV, Results of the Science and Technics, Series Inorganic Chemistry, Technetium Compounds and Their Application Sphere, VINITI, Moscow, 1984, (in Russian).

    Google Scholar 

  11. G. S. SINYAKOVA, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 4 (1987) 441.

    Google Scholar 

  12. G. S. SINYAKOVA, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 4 (1987) 448.

    Google Scholar 

  13. G. S. SINYAKOVA, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 6 (1987) 674.

    Google Scholar 

  14. G. S. SINYAKOVA, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 6 (1987) 681.

    Google Scholar 

  15. G. S. SINYAKOVA, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 6 (1987) 692.

    Google Scholar 

  16. B. KREBS, Z. anorg. und allgem. Chem., 380 (1971) 146.

    Google Scholar 

  17. S. I. GINZBURG, A. A. EZERSKAYA, I. V. PROKOFYEV, A. V. FEDORENKO, V. I. SHLENSKAYA, N. K. BELSKAYA, Analytical Chemistry of Platinum Metals, Nauka, Moscow, 1972, (in Russian).

    Google Scholar 

  18. V. M. SKORIKOV, A. V. SHEVCHUK, N. I. NELYANINA, Zh. Neorg. Khim., 33 (1988) 2467.

    Google Scholar 

  19. H. BEYER, O. GLEMSER, B. KRESS, Angew. Chem., 80 (1968) 286.

    Google Scholar 

  20. B. KREBS, A. MUELLER, H. BEVER, Inorg. Chem., 8 (1969) 436.

    Google Scholar 

  21. H. BEYER, O. GLEMSER, B. KREBS, G. WAGNER, Z. Anorg. Allgem. Chem., 376 (1970) 87.

    Google Scholar 

  22. H. SELIG, S. FRIED, Inorg. Nucl. Chem. Lett., 7 (1971) 318.

    Google Scholar 

  23. I. R. BEATTIE, G. A. OZIN, J. Chem. Soc. (A), 17 (1969) 2615.

    Google Scholar 

  24. M. E. POLOZNIKOVA, O. I. KONDRATOV, V. V. FOMICHEV, Zh. Neft. Khim., 33 (1988) 2526.

    Google Scholar 

  25. L. V. BORISOVA, A. N. YERMAKOV, Analytical Chemistry of Rhenium, Nauka, Moscow, 1974.

    Google Scholar 

  26. R. G. BROWN, S. D. ROSS, Spectochim. Acta, 28A (1972) 1263.

    Google Scholar 

  27. J. U. MONDAL, F. A. SHULTZ, T. D. BRENNAN, W. R. SCHEIDT, Inorg. Chem., 27 (1988) 3950.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sinyakova, G.S. Technetium(VII): Analysis of the possible structure of the higher oxide in various states. Journal of Radioanalytical and Nuclear Chemistry, Articles 158, 261–271 (1992). https://doi.org/10.1007/BF02047113

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02047113

Keywords

Navigation