Skip to main content
SpringerLink
Log in

Structural investigation of dibenzyltin(IV) complexes of carbohydrates

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Dibenzyltin(IV) complexes of carbohydrate derivatives were prepared and studied by Mössbauer and FTIR spectroscopy and by thermogravimetry. The Mössbauer studies indicated that the reaction between dibenzyltin(IV)-dichloride and sugar-type ligands led to reaction products containing tin(IV)-oxide. beside the dibenzyltin(IV) sugar complex. These two type of species were shown to be in weak interaction. Comparison of the experimental quadrupole splitting values with those calculated on the basis of the partial quadrupole splitting concept revealed the steric arrangements of the coordination sphere of tin(IV) in the sugar complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. R. SIEBENLIST, F. TAKETA, Toxicol. Appl. Pharmacol., 58 (1981) 67.

    Article  PubMed  Google Scholar 

  2. A. A. ALI, R. K. UPRETI, A. M. KIDWAY, Toxicol. Lett., 38 (1987) 13 A. A. ALI, R. K. upRETI, A. M. KIDWAY, Bull Environ. Contam. Toxicol., 44 (1990) 29.

    Article  PubMed  Google Scholar 

  3. A K. SAXENA, F. HUBER, Coord., Chem. Rev., 95 (1989) 109, and references therein.

    Google Scholar 

  4. P. SMITH, L. SMITH, Chem. Ber., 208 (1975).

  5. A. PATEL, C. POLLER, Rev. Silicon, Germanium, Tin, Lead Compd., 8 (1985) 263.

    Google Scholar 

  6. S. DAVID, C. PASCARD, M. CESARIO, Nouv. J. Chim., 3 (1979) 63.

    Google Scholar 

  7. T. S. CAMERON, P. K. BAKSHI, R. THANGARASA, T. B. GRINDLEY, Can. J. Chem., 70 (1992) 1623.

    Google Scholar 

  8. C. W. HOLZAPFEL, J. M. KOEKEMOER, C. F. MARAIS, C. J. KRUGER, J. A. PRETORIUS, S. Afr. J. Chem., 35 (1982) 80.

    Google Scholar 

  9. A. G. DAVIES, A. J. PRICE, H. H. DAWES, M. B. HURSTHOUSE, J. Chem. Soc. Dalton Trans, (1986) 297.

  10. T. B. GRINDLEY, R. D. CURTIS, R. THANGARASA, R. E. WASYLISHEN, Can. J. Chem., 68 (1990) 2102.

    Google Scholar 

  11. T. B. GRINDLEY, R. E. WASYLISHEN, R. THANGARASA, W. P. POWER, R. D. CURTIS, Can. J. Chem., 70 (1992) 205.

    Google Scholar 

  12. J. D. DONALDSON, S. M. GRIMES, L. PELLERITO, M. A. GIRASOLO, P. J. SMITH, A. CAMBRIA, M. FAMÁ, Polyhedron, 6 (1987) 383.

    Article  Google Scholar 

  13. L. NAGY, L. KORECZ, I. KIRICSI, L. ZSIKLA, K. BURGER, Struc. Chem., 2 (1991) 231.

    Google Scholar 

  14. K. BURGER, L. NAGY, N. BUZÁS, A. VÉRTES, H. MEHNER, J. Chem. Soc. Dalton Trans., (1993) 2499.

  15. N. BUZÁS, B. GYURCSIK, L. NAGY, Ying-Xia ZHANG, L. KORECZ, K. BURGER, Inorg. Chim Acta, 218 (1994) 65.

    Article  Google Scholar 

  16. B. GYURCSIK, N. BUZÁS, T. GAJDA, L. NAGY, E. KUZMANN, A VÉRTES, K. BURGER, Z. Naturforsch, (1994).

  17. L. NAGY, B. GYURCSIK, K. BURGER, S. YAMASHITA, T. YAMAGUCHI, H. WAKITA, M. NOMURA, Inorg. Chim. Acta., (1994).

  18. K. SISHIDO, Y. TAKEDA, Z. KIMUGAWA, J. Am. Chem. Soc., 83 (1961) 538.

    Article  Google Scholar 

  19. G. M. BANCROFT, V. G. KUMAR DAS, T. K. SHAM, M. G. CLARK, J. Chem. Soc. Dalton Trans., (1976) 643.

  20. G. M. BANCROFT, Mössbauer Spectroscopy: An Introduction for Inorganic Chemists and Geochemists, McGraw-Hill, London, 1973.

    Google Scholar 

  21. L. KORECZ, A. A. SAGHIER, K. BURGER, A. TZSCHACH, A. JURKSCHAT, Inorg. Chim. Acta, 58 (1982) 243.

    Article  Google Scholar 

  22. G. B. DEACON, R. J. PHILLIPS, Coord. Chem. Rev., 33 (1980) 227.

    Article  Google Scholar 

  23. G. K. SANDHU, R. GUPTA, S. S. SANDHU, R. V. PARISH, Polyhedron, 4 (1985) 81, and references therein.

    Article  Google Scholar 

  24. R. BARBIERI, A. SILVESTRI, F. HUBER, C-D. HAGER, Canad. J. Spectrosc., 26 (1981) 194.

    Google Scholar 

Download references

Author information

Author notes

  1. M. A. Pujar

    Present address: Department of Chemistry, University of Gulbarga, India

Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, A. József University, P.O. Box 440, H-6701, Szeged, Hungary

    N. Buzás, M. A. Pujar & L. Nagy

  2. Department of Nuclear Chemistry, L Eötvös University, Budapest, Hungary

    A. Vértes & E. Kuzmann

  3. Bundesanstalt für Materialforschung und-prüfung, Berlin-Adlershof, Germany

    H. Mehner

Authors
  1. N. Buzás
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Pujar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Nagy
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Vértes
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. Kuzmann
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. H. Mehner
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Buzás, N., Pujar, M.A., Nagy, L. et al. Structural investigation of dibenzyltin(IV) complexes of carbohydrates. Journal of Radioanalytical and Nuclear Chemistry, Articles 189, 237–245 (1995). https://doi.org/10.1007/BF02042602

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02042602

Keywords

Search

Navigation