Skip to main content
Log in

Spectral properties and kinetics of cationic transients generated in electron-pulse irradiated liquid alkanes

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Optical absorption spectra of radical cations of n-C7-to n-C16-alkanes, cyclohexane and methylcyclohexane were observed in electron-irradiated liquid alkanes. Spectral properties of these radical cations their fragmentation pattern and electron transfer reactions are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. P. W. F. LOUWRIER, W. H. HAMILL, J. Phys. Chem., 72 (1968) 3878.

    Google Scholar 

  2. H. A. GILLIS, N. V. KLASSEN, R. J. WOODS, Can. J. Chem., 55 (1977) 2022.

    Google Scholar 

  3. R. MEHNERT, O. BREDE, J. BÖS, Z. Chem., 17 (1977) 268.

    Google Scholar 

  4. J. T. WANG, F. WILLIAMS, Chem. Phys. Lett., 82 (1981) 1777.

    Google Scholar 

  5. K. TORIYAMA, K. NUNONE, M. IWASAKI, J. Phys. Chem., 85 (1981) 2149.

    Google Scholar 

  6. K. TORIYAMA, K. NUNONE, M. IWASAKI, J. Chem. Phys., 77 (1982) 5891.

    Google Scholar 

  7. T. SHIDA, Y. TAKEMURA, Radiat. Phys. Chem., 21 (1983) 157.

    Google Scholar 

  8. P. P. INFELTA, S. J. RZAD, J. Chem. Phys., 58 (1973) 3775.

    Google Scholar 

  9. R. C. BENZ, R. C. DUNBAR, J. Am. Chem. Soc., 101 (1979) 6363.

    Google Scholar 

  10. M. MEOT-NER (MAUTNER), L. W. SIECK, P. AUSLOOS, J. Am. Chem. Soc., 103 (1981) 5342.

    Google Scholar 

  11. K. TORIYAMA, K. NUNONE, M. IWASAKI, J. Chem. Phys., 77 (1982) 5891.

    Google Scholar 

  12. A. LUND, M. LINDGREN, G. DOLIVO, M. TABATA, Radiat. Phys. Chem., 26 (1985).

  13. R. MEHNERT, O. BREDE, W. NAUMANN, Ber. Bunsenges. Phys. Chem., 88 (1984) 71.

    Google Scholar 

  14. R. MEHNERT, O. BREDE, W. NAUMANN, Ber. Bunsenges. Phys. Chem., 89 (1985) 1031.

    Google Scholar 

  15. J. L. HOLMES, P. C. BURGERS, M. Y. A. MOLLAH, P. WOLKOFF, J. Am. Chem. Soc., 104 (1982) 2879.

    Google Scholar 

  16. K. NUNONE, K. TORIYAMA, M. IWASAKI, Chem. Phys. Lett., 105 (1984) 414.

    Google Scholar 

  17. R. MEHNERT, O. BREDE, W. NAUMANN, Radiat. Phys. Chem., 26 (1985) 499.

    Google Scholar 

  18. M. P. de HAAS, J. M. WARMAN, P. P. INFELTA, A. HUMMEL, Chem. Phys. Lett., 31 (1975) 382.

    Google Scholar 

  19. J. M. WARMAN, in The Study of Fast Processes and Transient Species by Electron Pulse Radiolysis, J. H. BAXENDALE, F. BUSI (Eds), D. REIDEL, Dordrecht, 1982.

    Google Scholar 

  20. R. MEHNERT, O. BREDE, J. BÖS, W. NAUMANN, Ber. Bunsenges. Phys. Chem., 83 (1979) 992.

    Google Scholar 

  21. R. MEHNERT, O. BREDE, W. NAUMANN, Ber. Busneges. Phys. Chem., 86 (1982) 525.

    Google Scholar 

  22. V. G. LEVICH, R. R. DOGONADZE, Coll. Czech. Chem. Comm. 26 (1961) 193.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mehnert, R., Brede, O. & Naumann, W. Spectral properties and kinetics of cationic transients generated in electron-pulse irradiated liquid alkanes. Journal of Radioanalytical and Nuclear Chemistry, Articles 101, 307–318 (1986). https://doi.org/10.1007/BF02042432

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02042432

Keywords

Navigation