Abstract
A method for direct analysis of the curves of potentiometric (pH) measurements of equimolar Mz++HnL chelating systems has been worked out. It is based on the balance of ionic charges and the mass balances of metal ion, ligand and hydrogen. The results of the study of Ca(II), Nd(III) and Pu(III) chelates with DTPA are given.
Similar content being viewed by others
References
J. INCZÉDY, Analytical Applications of Complex Equilibria, Akadémiai Kiadó, Budapest, 1976.
G. ANDEREGG, P. NAEGELI, F. MUELLER, G. SCHWARZENBACH, Helv. Chim. Acta, 42 (1959) 827.
R. HARDER, S. CHABEREK, J. Inorg. Nucl. Chem., 11 (1959) 197.
T. MOELLER, L. C. THOMPSON, J. Inorg. Nucl. Chem., 24 (1962) 499.
J. L. RYAN, E. J. WHEELWRIGHT, Application of Anion Exchange to the Reprocessing of Plutonium, 2nd UN Conf., Vol. 17, P/1915, Geneva, 1958.
A. POCZYNAJŁO, The Study of Reductive Reextraction of Plutonium in the Purex Process, Rep. INCT-2020/II/C/B, 1985 (Polish).
A. E. MARTELL, R. M. SMITH, Critical Stability Constants, Vol. 1, Amino Acids, Plenum Press, New York-London, 1974.
D. D. PERRIN, Stability Constants of Metal-Ion Complexes. Part B. Organic Ligands, Pergamon Press, New York, 1979.
J. KRAGTEN, Atlas of Metal-Ligand Equilibria in Aqueous Solution, J. Wiley and Sons, New York, 1978.
S. CHABEREK, A. E. FROST, M. A. DORAN, N. J. BICKNELL, J. Inorg. Nucl. Chem., 11 (1959) 184.
A. I. MOSKVIN, Radiokhimiya, 13 (1971) 575.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Poczynajło, A., Janiszewski, Z. Potentiometric determination of Ca(II), Nd(III) and Pu(III) chelates formed by diethylenetriaminepentaacetic acid. Journal of Radioanalytical and Nuclear Chemistry, Articles 125, 189–202 (1988). https://doi.org/10.1007/BF02041765
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02041765