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Extraction chromatography in the TBP-HNO3 system

III. Application of the TBP/XAD-4 column for analytical separation of uranium, neptunium, plutonium and americium

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Abstract

As an application of a TBP/XAD-4 column for the analytical separation of uranium, neptunium, plutonium and americium, the elution behavior of these elements as a function of their redox reactions has been studied. Subsequently, two effective procedures to carry out a quantitative separation of the actinide elements from each other were established by combining extraction chromatography in the TBP-HNO3 system and the redox reactions of the actinide elements.

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Author notes

  1. J. Serrano

    Present address: Special Projects Coordination, National Institute for Nuclear Research, Sierra Mojada 447, Lomas de Barrilaco, 11000, México, D.F.

Authors and Affiliations

  1. Department of Chemistry, Japan Atomic Energy Research Institute, Tokai-mura, Naka-gun, 319-11, Ibaraki-ken, (Japan)

    J. Serrano & T. Kimura

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  1. J. Serrano
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  2. T. Kimura
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Serrano, J., Kimura, T. Extraction chromatography in the TBP-HNO3 system. Journal of Radioanalytical and Nuclear Chemistry, Articles 172, 97–105 (1993). https://doi.org/10.1007/BF02040666

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  • DOI: https://doi.org/10.1007/BF02040666

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