Skip to main content
Log in

Isotope exchange between 12-molybdocerate(IV) and sodium molybdate-99Mo in aqueous media

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

12-molybdocerate(IV) gel labelled with99Mo has been prepared via isotope exchange between a column of inactive molybdate matrix and a mobile solution of99-Mo-sodium molybdate(VI) in 0.1 mol·dm−3 HNO3. The composition and nature of the reaction mixture, concentration of Mo(VI) in the reactants, reaction temperature and/or drying temperature of the gel matrix on the exchange yeild of99Mo and time of reaction are explored using the batch equilibration and/or the chromatographic column methods. The obtained material is evaluated for use in preparation of elution-type99Mo-99mTc generators.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. E. Boyd, Radiochim. Acta, 30 (1982) 123.

    Google Scholar 

  2. V. J. Molinski, Intern. J. Appl. Radiation Isotopes, 33 (1982) 811.

    Google Scholar 

  3. K. Kristensen, Technical Rept. Serries No. 194-STI/DOC/194, IAEA, Vienna, 1979.

    Google Scholar 

  4. V. S. Garimella Rayudu (Ed.), Radiotracers for Medical Application, Vol. 2, CRC, Boca Raton, 1983.

    Google Scholar 

  5. R. M. Stemple, Two Medical Diagnostic Isotopes68Ga and99mTc: A Bibliography, Report ORNL TM-2091.

  6. Fission Molybdenum for Medical Use, IAEA TEC DOC-515, IAEA, Vienna, 1989.

  7. H. Arino, H. H. Kramer, Intern. J. Appl. Radiaton Isotopes, 26 (1975) 301.

    Google Scholar 

  8. M. A. El-Absy, H. F. Aly, Radiochim. Acta, 57 (1992) 215.

    Google Scholar 

  9. M. A. El-Absy, Radiochim. Actas, 55 (1991) 23.

    Google Scholar 

  10. J. V. Evans, P. W. Moore, M. E. Shying, J. M. Sodeau, Appl. Radiation Isotopes, 38 (1987) 19.

    Google Scholar 

  11. P. W. Moore, M. E. Shying, J. M. Sodeau, J. V. Evans, D. J. Maddailena, K. H. Farrington, Appl. Radiation Isotopes, 38 (1987) 35.

    Google Scholar 

  12. M. A. Et-Absy, S. El-Bayoumy, Isotopenpraxis, 26 (1990) 60.

    Google Scholar 

  13. M. A. El-Absy, I. M. El-Naggar, A. I. Audah, J. Radional. Nucl. Chem., 173 (1993) 185.

    Google Scholar 

  14. D. V. S. Narasimhan, Kum. Vanaja, R. S. Mani, J. Radional. Nucl. Chem., 85 (1984) 345.

    Google Scholar 

  15. P. Vanaja, N. Ramamoorthy, S. P. Iyer, R. S. Mani, Radiochim. Acta, 42 (1987) 49.

    Google Scholar 

  16. M. A. El-Absy, I. M. El-Naggar, A. I. Audah, J. Radional. Nucl. Chem., 183 (1994) 339.

    Google Scholar 

  17. J. H. Zaidi, H. M. A. Karim, M. Arif, I. H. Qureshi, Radiochim. Acta, 49 (1990) 107.

    Google Scholar 

  18. A. Chearfield, Inorganic Ion Exchange Materials, CRC Press, Inc. Boca Raton, 1982.

    Google Scholar 

  19. M. Qureshi, K. G. Varshney, Inorganic Ion Exchangers in Chemical Analysis, CRC Pres, Boca Raton, Inc. Ann Arbor, Boston, 1991.

    Google Scholar 

  20. K. I. N. Rao, K. R. Blasubramanian, J. P. Shukla, Nuclear and Radiochemistry Symp., Vol. 1, Bombay, India, 21–24 Dec. 1992, p. 314.

    Google Scholar 

  21. J. Satyanarayama, G. S. Mirthy, A. Dash, Nuclear and Radiochemistry Symp., Vol. 1, Bombay, India 21–24 Dec. 1992, p. 423.

    Google Scholar 

  22. A. Moran, J. A. Sonchez-Cabeza, M. Blanco, P. I. Mitchell, Radiochim. Acta, 62 (1993) 159.

    Google Scholar 

  23. T. S. Bondarenko, F. S. Bojchinova, Zh. Prickl. Khim., 66 (1993) 2213.

    Google Scholar 

  24. T. S. Bondarenko, F. S. Bojchinova, Zh. Prikl. Khim., 65 (1992) 2677.

    Google Scholar 

  25. M. A. El-Absy, M. Abou El-Enein, H. El-Sand, M. Haieh, 6th Conf. of Nuclear Sciences and Applications, Cairo, Egypt, 15–20 March 1996.

  26. Weng-Haomin, You-xin, J. Nucl. Radiochem., 14 (1992) 184.

    Google Scholar 

  27. N. Ikeda, M. Yoshikawa, S. Murakami, J. Kunika, J. Radional. Nucl. Chem., 122 (1988) 27.

    Google Scholar 

  28. I. K. Spigin, F. N. Abanina, J. Analyt. Chem. USSR 39 (1985) 1456.

    Google Scholar 

  29. P. Daudel, Radioactive Tracers in Chemistry and Industry, Charles Griffin Company Limited, London, 1960.

    Google Scholar 

  30. An N. Nesmeyanov, Radiochemistry, Mir, Moscow, 1974 (in Russian).

    Google Scholar 

  31. G. Marcu Chimie Elementelor Radioactive, Editura Didactica si Pedagogicia, Bucuresti, 1971.

    Google Scholar 

  32. R. S. Rai, D. R. Nethway, W. C. Wahl., Radiochim. Acta, 5 (1966) 30.

    Google Scholar 

  33. M. A. El-Absy, N. Z. Misak, H. F. Aly, J. Radioanal. Nucl. Chem. 100 (186) 73.

  34. E. B. Sandell, Colorimetric Determination of Traces of Metals, Interscience Publicatons, Inc., New York, 1959.

    Google Scholar 

  35. M. A. El-Absy, I. M. El-Naggar, M. Raieh, H. F. Aly, Colloids and Surfaces, A 100 (1995) 105.

    Google Scholar 

  36. S. A. Cotton, F. A. Hart The Heavy Transition Elements, MacMillan, London, 1975.

    Google Scholar 

  37. H. A. C. McKay, Nature, 142 (1938) 997.

    Google Scholar 

  38. R. K. Barnes, R. E. Boyd, rept. IEA-SR-131/38.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

El-Absy, M.A., El-Enein, M.A., Raieh, M. et al. Isotope exchange between 12-molybdocerate(IV) and sodium molybdate-99Mo in aqueous media. J Radioanal Nucl Chem 218, 157–168 (1997). https://doi.org/10.1007/BF02039328

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02039328

Keywords

Navigation