Journal of Radioanalytical and Nuclear Chemistry

, Volume 120, Issue 1, pp 195–203 | Cite as

Synergistic extraction of uranium(VI) by lower fatty acids in the presence of amines and its separation from some lanthanides

  • Asha Jain
  • O. V. Singh
  • S. N. Tandon
Article

Abstract

The synergistic extraction of UO2(II) in a chloroform solution of propionic, butyric and valeric acids (HA) in the presence of some aliphatic and aromatic amines (B) has been investigated. The effect of various variables, like the concentration of hydrogen and metal ion, carboxylic acid and amine on extraction has been studied. The composition of the synergistic adducts has been determined on the basis of slope analysis and the species is proposed to be UO2A2B2 2HA. The extraction constants (Kex) have been calculated and the relative effectiveness of the amines as synergists is compared. Extraction data have been used to separate UO2(II) from lanthanides, like Ce(III), Nd(III), Gd(III), Eu(III) and Yb(III).

Keywords

Hydrogen Physical Chemistry Inorganic Chemistry Chloroform Uranium 

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References

  1. 1.
    R. PIETSCH, H. SINIC, Anal. Chim. Acta., 49 (1970) 51.Google Scholar
  2. 2.
    I. V. PYATNITSKII, AIE OMODE, V. V. SUKHAN, V. A. FRANKOVSKII, Zh. Analit. Khim., 28 (1973) 50.Google Scholar
  3. 3.
    V. V. SUKHAN, I. V. PYATNITSKII, V. A. FRANKOVSKII, Zh. Analit. Khim., 28 (1973) 541.Google Scholar
  4. 4.
    I. V. PYATNITSKII, V. V. SUKHAN, V. B. ISCHENKO, Ukr. Khim. Zh., 43 (197) 411.Google Scholar
  5. 5.
    I. V. PYATNITSKII, V. I. SIMONENKO, Ukr. Khim. Zh., 43 (1977) 203.Google Scholar
  6. 6.
    S. K. GOGIA, D. SINGH, O. V. SINGH, S. N. TANDON, Solvent Extr. Ion Exch. 2 (1984), No. 6, 899.Google Scholar
  7. 7.
    G. SCHWARZENBACH, H. FLASCHKA, Complexometric Titrations, 2nd ed., London, 1969, p. 229.Google Scholar
  8. 8.
    KINNUNEN, WENNERSTRAND, Chemist Analyst, 46 (1957) 92.Google Scholar
  9. 9.
    J. S. FRITZ, Anal. Chem., 22 (1950) 1028.Google Scholar
  10. 10.
    S. K. GOGIA, D. SINGH, O. V. SINGH, S. N. TANDON, Talanta, 34 (1987) 303.Google Scholar
  11. 11.
    I. V. PYATNITSKII, A. OMODE, V. V. SUKHAN, Zh. Analit. Khim., 28 (1973) 2317.Google Scholar
  12. 12.
    B. S. SUNDER, G. V. V. RAO, E. S. KUMARI, V. MANGATHAYARAMMA, Ind. J. Chem., 24A (1985) 505.Google Scholar

Copyright information

© Akadémiai Kiadó 1988

Authors and Affiliations

  • Asha Jain
    • 1
  • O. V. Singh
    • 1
  • S. N. Tandon
    • 1
  1. 1.Department of ChemistryUniversity of RoorkeeRoorkee 24(India)

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