Skip to main content
Log in

Studies on the radiolysis of U(VI)-thoron complex

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

This work is an investigation of the radiation stability of thoron-uranium complex. It deals mainly with the effect of absorbed dose on the absorption spectra of the complex at different complex concentrations. The radiolysis of the complex, was also investigated in presence of varying concentrations of ethanol and methanol. The decrease in absorbance at the characteristic peak as a function of absorbed dose, complex concentration, and alcohol concentration was used to calculate the G-value and the specific rate of bimolecular interaction of the complex molecule with water radiolysis products. The radiolysis mechanism was discussed in the light of the results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. SANGAL, Microchem. J., 7 (1965) 331.

    Google Scholar 

  2. H. PERRY, H. JOHN, Anal. Chem., 32 (1960) 612.

    Google Scholar 

  3. C. CROUTHAMEL, C. JOHNSON, Anal. Chem., 24 (1952) 1780.

    Google Scholar 

  4. H. ZITTEL, L. SCROGGIE, Anal. Chim. Acta, 40 (1968) 277.

    Google Scholar 

  5. J. SULLIVAN, S. GORDON, D. COHEN, W. MULAC, K. SCHMIDT, J. Phys. Chem., 80 (1976) 1684.

    Google Scholar 

  6. J. KOCHANNY, Anal. Chim. Acta, 33 (1965) 76.

    Google Scholar 

  7. V. SPITSYN, V. GROMOV, D. ABDULAEV, Dokl. Phys. Chem., 216 (1974) 475.

    Google Scholar 

  8. N. SOUKA, F. ABDEL-RAHIM, M. MAHMOUD, J. Radional. Nuclear Chem., 125 (1988) 47.

    Google Scholar 

  9. M. ANBAR, P. NETA, Int. J. Appl. Radiation Isotopes, 18 (1967) 493.

    Google Scholar 

  10. G. ADAMS, J. BOAG, B. MICHAEL, Trans. Faraday Soc., 61 (1965) 1417.

    Google Scholar 

  11. R. MATHEWS, D. SANGSTER, J. Phys. Chem., 69 (1965) 1938.

    Google Scholar 

  12. H. JAMES, F. DAVID, Principles of Radiation Chemistry, Edward Arnold Ltd., London, 1970.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

National Center of Radiation Research and Technology.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Souka, N., Abdel-Rahim, F. & Mahmoud, M.R. Studies on the radiolysis of U(VI)-thoron complex. Journal of Radioanalytical and Nuclear Chemistry, Articles 130, 177–185 (1989). https://doi.org/10.1007/BF02037711

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02037711

Keywords

Navigation