Abstract
This work is an investigation of the radiation stability of thoron-uranium complex. It deals mainly with the effect of absorbed dose on the absorption spectra of the complex at different complex concentrations. The radiolysis of the complex, was also investigated in presence of varying concentrations of ethanol and methanol. The decrease in absorbance at the characteristic peak as a function of absorbed dose, complex concentration, and alcohol concentration was used to calculate the G-value and the specific rate of bimolecular interaction of the complex molecule with water radiolysis products. The radiolysis mechanism was discussed in the light of the results.
Similar content being viewed by others
References
S. SANGAL, Microchem. J., 7 (1965) 331.
H. PERRY, H. JOHN, Anal. Chem., 32 (1960) 612.
C. CROUTHAMEL, C. JOHNSON, Anal. Chem., 24 (1952) 1780.
H. ZITTEL, L. SCROGGIE, Anal. Chim. Acta, 40 (1968) 277.
J. SULLIVAN, S. GORDON, D. COHEN, W. MULAC, K. SCHMIDT, J. Phys. Chem., 80 (1976) 1684.
J. KOCHANNY, Anal. Chim. Acta, 33 (1965) 76.
V. SPITSYN, V. GROMOV, D. ABDULAEV, Dokl. Phys. Chem., 216 (1974) 475.
N. SOUKA, F. ABDEL-RAHIM, M. MAHMOUD, J. Radional. Nuclear Chem., 125 (1988) 47.
M. ANBAR, P. NETA, Int. J. Appl. Radiation Isotopes, 18 (1967) 493.
G. ADAMS, J. BOAG, B. MICHAEL, Trans. Faraday Soc., 61 (1965) 1417.
R. MATHEWS, D. SANGSTER, J. Phys. Chem., 69 (1965) 1938.
H. JAMES, F. DAVID, Principles of Radiation Chemistry, Edward Arnold Ltd., London, 1970.
Author information
Authors and Affiliations
Additional information
National Center of Radiation Research and Technology.
Rights and permissions
About this article
Cite this article
Souka, N., Abdel-Rahim, F. & Mahmoud, M.R. Studies on the radiolysis of U(VI)-thoron complex. Journal of Radioanalytical and Nuclear Chemistry, Articles 130, 177–185 (1989). https://doi.org/10.1007/BF02037711
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02037711