The application of micro-column solid phase extraction techniques for the determination of rare earth elements in actinide containing matrices

  • K. P. Carney
  • D. G. Cummings
Radioanalytical Methods Applied to the Nuclear Fuel Cycle (Continued)


The design and characterization of an argon segmented-solid phase extraction system is described. A 200 ul volume micro-column has been constructed for the preconcentration of rare earth elements (REEs) from salt matrices containing uranium. An inductively coupled plasma atomic emission spectrometer has been utilized for simultaneous detection of Sr, Y and the REEs (namely Ce, Eu, La, Nd, Pr, Sm) at levels ranging from 5- to 2000 ppm in LiC1/KCl samples containing U. Preconcentration factors of 100 fold have been demonstrated. The precision, linear dynamic range and column performance of the system will be presented.


Argon Inorganic Chemistry Uranium Solid Phase Extraction Phase Extraction 
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  1. 1.
    E.H. VAN VEEN, M.T.C. DE LOOS-VOLLEBREGT, A.P. WASSINK, H. KALTER, Anal. Chem., 18 (1993) 1643.Google Scholar
  2. 2.
    I.B. BRENNER, R. BINSTOCK, E. DORFMAN, L. HALICZ ICP Information News Letters, 18 (1993) 473.Google Scholar
  3. 3.
    P.A. VIEIRA, H. ZHIZHUANG, S. CHAN, A. MONTASER, Appl. Spectros., 40 (1986) 1141.CrossRefGoogle Scholar
  4. 4.
    C. LITEAU, I. RICA, Statistical Theory and Methodology of Trace Analysis John Wiley and Sons, New York (1980).Google Scholar
  5. 5.
    L.K. OLSEN, J.A. CARUSO, J.T. CREED, K.A. WOLNIK, F.L. FRICKE, Appl. Spectrosc., 44 (1990) 716.CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó 1995

Authors and Affiliations

  • K. P. Carney
    • 1
  • D. G. Cummings
    • 1
  1. 1.Argonne National Laboratory-WestIdaho Falls(USA)

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