Abstract
A radiotracer method was used for investigation of the adsorption and desorption of radium on stream sediments under conditions similar to those prevailing in waste and surface waters. The effects of pH, ionic strength and Ca2+ or SO 2−4 ions were studied. The results were compared with analogous data characterizing radium interaction with model solids representing components of the sediments. It has been found that the adsorption affinity of the sediments for radium cannot be easily derived from their composition or other properties. No simple correlation with specific surface area, organic matter, oxidic coatings or other components of the sediments was observed. However, an exceptional role of barite (barium sulfate) in the sediments was noted. In the presence of sulfate ions (60 mg/l) this component was responsible for the uptake of predominant or at least significant part of radium, depending on the barite content of sediments. In the absence of added sulfate ions, the adsorption of radium at ph 5–9 on sediments containing barite was lower than on similar sediments without this component, indicating that other components may be more efficient in radium adsorption.
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References
E. C. TSIVOGLOU, J. Water Pollut. Control Fed., 35 (1963) 242.
E. HANSLIK, A. MANSFELD, Final Report No. R-502004, Water Research Institute, Prague, 1973 (in Czech).
USEPA, Potential Health and Environmental Hazard of Uranium Mine Wastes, EPA 520/1-83-007, U.S. Environmental Protection Agency, Washington 1983.
P. BENEŠ, Physico-chemical Forms and Migration in Continental Waters of Radium from Uranium Mining and Milling. In: Environmental Migration of Long-lived Radionuclides, IAEA, Vienna, 1982, p. 3.
F. ŠEBESTA et al., Environ. Sci. Technol., 15 (1981) 71.
P. BENEŠ et al., Water Res., 17 (1983) 619.
P. BENEŠ, P. STREJC, Z. LUKAVEC, J. Radioanal. Nucl. Chem. 82 (1984) 275.
P. BENEŠ, Z. BOROVEC, P. STREJC, J. Radioanal. Nucl. Chem. 89 (1985) 339.
P. BENEŠ, Z. BOROVEC, P. STREJC, J. Radioanal. Nucl. Chem., 98 (1986) 91.
S. M. OAKLEY, P. O. NELSON, K. J. WILLIAMSON, Environ. Sci. Technol. 15 (1981) 474.
TANG HONG-XIAO, XUE HAN-BIN, Heavy Metals in the Environment. Proc. Int. Conf. Heidelberg 1983, pp. 884–887.
S. N. LUOMA, J. A. DAVIS, Marine Chem. 12 (1983) 159.
E. A. JENNE, Trace Element Sorption by Sediments and Soils-Sites and Processes. In: Symp. on Molybdenum in the Environment, W. CHAPELL, K. PETERSON (Eds), Vol. 2, Marcel Dekker, New York, 1977, p. 425.
F. ŠEBESTA, P. BENEŠ, J. SEDLÁČEK and B. HAVLÍK, Studies on the Source, Distribution, Movement and Deposition of Radium in Inland Waterways and Aquifers. Progress Report to the IAEA for the Research Contract No. 1729/R3/RB. Prague, June 1980.
F. M. NELSEN, F. T. EGGERTSEN, Anal. Chem., 30 (1958) 1387.
A. TESSIER, P. G. C. CAMPBELL, M. BISSON, Anal. Chem. 51 (1979) 844.
D. WEISS et al., Methods of Chemical Analysis of Silicate Rocks (in Czech). Central Geological Institute, Prague 1973.
LECO, Instruction Manual. LECO Corporation, 3000 Lakeview Avenue, Saint Joseph, Michigan, USA.
P. BENEŠ, V. MAJER, Trace Chemistry of Aqueous Solutions, Academia-Elsevier, Prague-Amsterdam, 1980.
BENEŠ et al., Water Res. 15 (1981) 1299.
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Beneš, P., Strejc, P. Interaction of radium with freshwater sediments and their mineral components. Journal of Radioanalytical and Nuclear Chemistry, Articles 99, 407–422 (1986). https://doi.org/10.1007/BF02037602
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DOI: https://doi.org/10.1007/BF02037602