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Catalytic and inhibitory effects of technetium on reduction processes

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Abstract

Interactions between technetium and some anthraquinones and tartrazin in the presence of tin(II) are described. It was found that whereas the reductive process between Sn(II) and 1-amino-4-hydroxyanthraquinone is catalyzed by technetium, the reduction of tartrazin is inhibited by this element. Study of such processes seems to indicate that the catalytic effect of technetium on the reduction processes is due to Tc(V) action whereas the inhibitory effect is due to the Tc(IV) species.

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References

  1. E. DEUTSCH, K. LIBSON, S. JURISSON, L. F. LINDOY, Progress in Inorganic Chemistry, Vol. 30, S. J. LIPPARD (Ed.) Interscience, New York, 1983.

    Google Scholar 

  2. F. GRASES, J. G. MARCH, Anal. Chem., 57 (1985) 1419.

    Article  Google Scholar 

  3. E. AMAT, J. G. MARCH, F. GRASES, in preparation.

  4. F. GRASES, J. G. MARCH, F. MATA, A. PENAFIEL, Bull. Chem. Soc. Japan, in press.

  5. F. GRASES, G. FAR, J. G. MARCH, Anal. Chim. Acta, 174 (1985) 163.

    Article  Google Scholar 

  6. F. GRASES, J. G. MARCH, F. MATA, A. PEÑAFIEL, Anal. Chim. Acta, 166 (1984) 71.

    Article  Google Scholar 

  7. Burger's Medicinal Chemistry, 4th ed., Wiley, New York, 1980.

  8. Y. P. SUSLOV, L. M. RAMAZANOV, V. A. BOROVINSKII, Radiokhimiya, 23 (1981) 721.

    Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Sciences, University of Palma de Mallorca, 07071, Palma de Mallorca, (Spain)

    F. Grases, C. Genestar, J. G. March & P. March

Authors
  1. F. Grases
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  2. C. Genestar
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  3. J. G. March
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  4. P. March
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Grases, F., Genestar, C., March, J.G. et al. Catalytic and inhibitory effects of technetium on reduction processes. Journal of Radioanalytical and Nuclear Chemistry, Articles 99, 391–396 (1986). https://doi.org/10.1007/BF02037600

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  • DOI: https://doi.org/10.1007/BF02037600

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