Abstract
The rate constants for thallium(I)-thallium(III) exchange with various alcohols in sulfuric acid solution were determined. In all cases involving alcohols, methanol, ethanol, 2-propanol, 2-methyl-2-propanol, the reaction rates were not accelerated. The larger the formation constants of solvato-complexes for 2-propanol and 2-methyl-2-propanol lead to lower reaction rates in the solution. The mechanism of the exchange reaction was also studied.
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References
P. STILSON, M. KAHN, J. Am. Chem. Soc., 75 (1953) 3579.
E. L. PURLEE, M. KAHN, J. L. RIEBSOMER, J. Am. Chem. Soc., 76 (1954) 3796.
R. W. DODSON, J. Am. Chem. Soc., 75 (1953) 1795.
K. NAKAMURA, K. HASEGAWA, J. Chem. Soc. Japan, 4 (1982) 700.
K. B. YATSIMIRSKII, L. I. BUDARIN, Russ. J. Inorg. Chem., 7 (1962) 560.
R. G. McGREGOR, D. R. WILES, J. Chem. Soc., (A) (1970) 323.
E. A. M. HUGHES, The Chemical Statics and Kinetic of Solutions, Academic Press, London and New York, 1971, p. 161.
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Hasegawa, K., Ikeda, K. Thallous-thallic exchange reaction in the sulfuric acid solution of some alcohols. Journal of Radioanalytical and Nuclear Chemistry, Articles 99, 379–384 (1986). https://doi.org/10.1007/BF02037598
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DOI: https://doi.org/10.1007/BF02037598