Skip to main content
SpringerLink
Log in

A study of changes in the yields of radiolytic products in two-phase systems with tributyl phosphate

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

With the aim of studying the effects of volume ratios and composition of the organic phase on the total yields of the main degradation products of tributyl phosphate (TBP) radiolysis, the following two-phase systems were used: water-TBP-carbon tetrachloride and water-TBP-n-alkane with various ratio of TBP in the organic phase and various volume ratios of organic-aqueous phases. We examined the influence of the distribution of two-phase systems components-precursors of radiolytic products on the total yields of the main radiolytic products and mechanism involved.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. W. SCHULZ, J. D. NAVRATIL, E. A. TALBOT, Science and Technology of Tributyl Phosphate, Vol. 1, Synthesis, Properties, Reactions and Analysis, CRC Press, Inc., Boca Raton, Florida, USA, 1984.

    Google Scholar 

  2. W. W. SCHULZ, J. D. NAVRATIL, E. A. TALBOT, Science and Technology of Tributyl Phosphate, Vol. 2, Applications of Tributyl Phosphate, CRC Press, Inc., Boca Raton, Florida, USA, 1986.

    Google Scholar 

  3. G. F. JEGOROV, Radiatsionnaya khimiya ekstraktsionnykh sistem, Energoatomizdat, Moscow, 1986.

    Google Scholar 

  4. A. S. SOLOVKIN, M. V. VLADIMIROVA, I. A. KULIKOV, Ekstrakciya ionov metallov mono-i-di-n-butilfosfornymi kislotami, Itogi nauki i tekhniki, Ser. Neorg. Khim., VINITI, Moscow, USSR, 1985, p. 12.

    Google Scholar 

  5. D. C. STEWART, H. W. CRANDALL, J. Am. Chem. Soc., 73 (1951) 1377.

    Article  Google Scholar 

  6. A. PETRU, P. RAJEC, R. ČECH, J. KURUC, J. Radioanal. Nucl. Chem., 129 (1989) 229.

    Article  Google Scholar 

  7. R. ČECH, P. RAČAY, F. MACÁŠEK, Radiat. Phys. Chem., 33 (1989) 109.

    Google Scholar 

  8. F. MACÁŠEK, Radiat. Phys. Chem., 23 (1984) 481.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Nuclear Chemistry, Faculty of Natural Sciences, Comenius University, 842 15, Bratislava, (Czecho-Slovakia)

    M. Hromadová & P. Rajec

  2. Hygiene and Epidemiology Research Institute, 8 Ruzinovska Str., 827 99, Bratislava, (Czecho-Slovakia)

    R. Čech

Authors
  1. M. Hromadová
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Čech
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Rajec
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hromadová, M., Čech, R. & Rajec, P. A study of changes in the yields of radiolytic products in two-phase systems with tributyl phosphate. Journal of Radioanalytical and Nuclear Chemistry, Articles 163, 99–105 (1992). https://doi.org/10.1007/BF02037484

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02037484

Keywords

Search

Navigation