Skip to main content
SpringerLink
Log in

Solid phase extraction for sample preparation in trace analysis of ionogenic compounds by capillary isotachophoresis

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Various sorbents recommended for solid phase extraction (SPE) in sample preparation procedures were studied for use in combination with capillary isotachophoresis (ITP). They were very efficient in achieving trace concentration levels (low ppb, i.e., low parts per 109) for different types of ITP analytes present in environmental and biological matrices. A macroporous carbon sorbent was convenient for sample preparation in ITP analysis of short chain fatty acids (C4−C9) in drinking water. Chelating sorbents based on hydroxyalkyl methacrylate matrix with salicylate, thioglycolate and 8-hydroxyquinolinate functionalities were found to be very suitable for preconcentration of heavy metals with an inherent sample clean-up. An octadecyl-bonded silica sorbent enabled in ITP a photometric detection of γ-aminobutyrate (labeled with a 2,4,6-trinitrophenyl group) at concentrations considerably lower than required for the determination of this amino acid in cerebrospinal fluid (∼5·10−8 mol/l).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. M. EVERAERTS, J. L. BECKERS, TH. P. E. M. VERHEGGEN, Isotachophoresis, Theory, Instrumentation and Applications, Elsevier, Amsterdam, Oxford, New York, 1976.

    Google Scholar 

  2. L. ARLINGER, J. Chromatogr., 91 (1974) 785.

    Article  Google Scholar 

  3. M. SVOBODA, J. VACÍK, J. Chromatogr., 119 (1976) 539.

    Article  Google Scholar 

  4. D. KANIANSKY, V. MADAJOVÁ, J. MARÁK, E. ŠIMUNIČOVÁ, I. ZELENSKÝ, V. ZELENSKÁ, J. Chromatogr., 390 (1987) 51.

    Article  PubMed  Google Scholar 

  5. P. BOČEK, M. DEML, P. GEBAUER, V. DOLNÍK, Analytická Kapilární Izotachoforéza, Academia, Prague, 1987.

    Google Scholar 

  6. J. MARÁK, J. LAŠTINEC, D. KANIANSKY, V. MADAJOVÁ, J. Chromatogr., 509 (1990) 287.

    Article  Google Scholar 

  7. P. BOČEK, M. DEML, B. KAPLANOVÁ, J. JANÁK, J. Chromatogr., 160 (1979) 1.

    Article  Google Scholar 

  8. F. E. P. MIKKERS, F. M. EVERAERTS, J. A. F. PEEK, J. Chromatogr., 168 (1979) 293.

    Article  Google Scholar 

  9. F. E. P. MIKKERS, F. M. EVERAERTS, J. A. F. PEEK, J. Chromatogr., 168 (1979) 317.

    Article  Google Scholar 

  10. V. DOLNÍK, M. DEML, P. BOČEK, J. Chromatogr., 320 (1985) 89.

    Article  PubMed  Google Scholar 

  11. J. C. GIDDINGS, J. High Resolut. Chromatogr. Commun., 10 (1987) 319.

    Article  Google Scholar 

  12. K. ZECH, R. W. FREI (Eds), Selective Sample Handling and Detection in High-Performance Liquid Chromatography, Part B, Elsevier, Amsterdam, Oxford, New York, Tokyo, 1989.

    Google Scholar 

  13. P. D. McDONALD (Ed.), Waters Sep-Pak Cartridge Applications Bibliography, 4th ed., Waters, Milford, 1986.

    Google Scholar 

  14. M. ZIEF, R. KISER (Eds), Solid Phase Extraction for Sample Preparation, J. T. Baker, Phillipsburg, 1988.

    Google Scholar 

  15. F. M. EVERAERTS, TH. P. E. VERHEGOEN, F. E. P. MIKKERS, J. Chromatogr., 169 (1979) 21.

    Article  Google Scholar 

  16. D. KANIANSKY, Thesis, Komenský University, Bratislava 1981.

  17. I. ZELENSKÝ, E. ŠIMUNIČOVÁ, V. ZELENSKÁ, D. KANIANSKY, P. HAVAŠI, P. CHALÁNI, J. Chromatogr., 325 (1985) 161.

    Article  Google Scholar 

  18. D. D. PERRIN, W. L. F. ARMAREGO, D. R. PERRIN, Purification of Laboratory Chemicals, Pergamon Press, Oxford, 2nd ed., 1980.

    Google Scholar 

  19. A. MIZUIKE, Enrichment Techniques for Inorganic Trace Analysis, Springer, Berlin, 1983.

    Google Scholar 

  20. D. R. KNAPP, Handbook of Analytical Derivatization Reactions, J. Wiley, New York, 1979.

    Google Scholar 

  21. A. ŠIŠKOVÁ, Graduation Report, Komenský University, Bratislava, 1988.

    Google Scholar 

  22. Separcol Preseparation Minicolumns, Centre of Chemical Research, Slovak Academy of Science, Bratislava, 1988.

  23. J. L. BECKERS, F. M. EVERAERTS, W. I. M. HOUTERMANS, J. Chromatogr., 76 (1973) 277.

    Article  PubMed  Google Scholar 

  24. M. KOVAL, D. KANIANSKY, M. HUTTA, R. LACKO, J. Chromatogr., 325 (1985) 151.

    Article  Google Scholar 

  25. T. BARTH, Anal. Chem., 59 (1987) 2232.

    Article  Google Scholar 

  26. M. HUTTA, E. ŠIMUNIČOVÁ, D. KANIANSKY, J. TKÁČOVÁ, J. BRTKO, J. Chromatogr., 470 (1989) 223.

    Article  PubMed  Google Scholar 

  27. O. CHIANTORE, I. NOVÁK, D. BEREK, Anal. Chem., 59 (1987) 1720.

    Article  PubMed  Google Scholar 

  28. I. ZELENSKÝ, D. KANIANSKY, P. HAVAŠI, TH. P. E. M. VERHEGGEN, F. M. EVERAERTS, J. Chromatogr., 470 (1989) 155.

    Article  Google Scholar 

  29. F. M. EVERAERTS, TH. P. E. M. VERHEGGEN, J. C. REIJENGA, G. V. A. ABEN, P. GEBAUER, P. BOČEK, J. Chromatogr., 320 (1985) 263.

    Article  PubMed  Google Scholar 

  30. T. HIROKAWA, T. MATSUKI, H. TAKEMI, Y. KISO, J. Chromatogr., 280 (1983) 233.

    Article  Google Scholar 

  31. G. P. GERRITS, F. J. TRIJBELS, L. A. MONNENS, F. J. GABREELS, R. A. DE ABREU, AD. G. THEUUWES, B. VAN RAAY-SELTEN, Clin. Chim. Acta, 182 (1989) 271.

    Article  PubMed  Google Scholar 

  32. Y. KAMISAKI, Y. TAKAO, T. ITOH, T. SHIMOMURA, K. TAKAHASHI, N. UEHARA, Y. YOSKHINO, J. Chromatogr., 529 (1990) 417.

    PubMed  Google Scholar 

  33. T. AGETA, H. MIKASA, K. KOJIMA, H. KODAMA, J. Chromatogr., 233 (1982) 361.

    PubMed  Google Scholar 

  34. W. L. CAUDILL, R. M. WIGHTMAN, Anal. Chim. Acta, 141 (1982) 269.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Natural Sciences, Comenius University, Mlynská Dolina CH-2, CS-842 15, Bratislava, (Czecho-Slovakia)

    M. Hutta, D. Kaniansky, E. Šimuničová, V. Zelenská, V. Madajová & A. Šišková

Authors
  1. M. Hutta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. Kaniansky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Šimuničová
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. Zelenská
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. Madajová
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Šišková
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hutta, M., Kaniansky, D., Šimuničová, E. et al. Solid phase extraction for sample preparation in trace analysis of ionogenic compounds by capillary isotachophoresis. Journal of Radioanalytical and Nuclear Chemistry, Articles 163, 87–98 (1992). https://doi.org/10.1007/BF02037483

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02037483

Keywords

Search

Navigation