Abstract
The characteristics of uncatalyzed bromate oscillator are altered in presence of γ-irradiation. These alterations could not be accounted for in terms of substrates acting as scavengers for hydrogen atoms. The alteration of the effective activity of the “key species” in presence of γ-irradiation can also account for the changes observed in the oscillation characteristics.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
E. KÖRÖS, M. ORBÁN, Nature, 273 (1978) 559.
M. ORBÁN, E. KÖRÖS, J. Phys. Chem., 82 (1978) 1672.
E. KÖRÖS, M. ORBÁN, I. HABON, J. Phys. Chem., 84 (1980) 559.
K. BAR-ELI, S. HADDAD, J. Phys. Chem., 83 (1979) 2952.
Z. VÁRADI, M. T. BECK, J. Chem. Soc. Chem. Commun., (1970) 30.
L. TREINDL, P. FABIN, Coll. Czech. Chem. Commun., 45 (1980) 1168.
R. M. NOYES, Faraday Symposia of the Chemical Society, Physical Chemistry of Oscillatory Phenomena, Vol. 9, The Faraday Division, Chemical Society, London, 1974, p. 84.
Z. NOSZTICZIUS, J. Am. Chem. Soc., 101 (1979) 3660.
N. GANAPATHISUBRAMANIAN, R. M. NOYES, J. Phys. Chem., 86 (1982) 5155.
P. RUOFF, Z. Naturforsch., 38A (1983) 974.
P. RUOFF, B. SCHWITTERS, J. Phys. Chem., 88 (1984) 6424.
B. SCHWITTERS, P. RUOFF, J. Phys. Chem., 90 (1986) 2497.
J. W. T. SPINKS, R. J. WOODS, An Introduction to Radiation Chemistry, J. Wiley and Sons, New York, 1964.
K. V. S. RAMA RAO, D. PRASAD, Kinetics of Physicochemical Oscillations, Vol. 3, Proc. Symp. Aachen, 1979, p. 724.
E. KÖRÖS, G. PUTIRSKAYA, M. VARGA, Acta Chim. Acad. Sci. Hung., 110 (1982) 295.
M. KRISHNARATNAM, B. VISWANATHAN, R. RAMASWAMY, Indian J. Tech., 25 (1987) 191.
E. KÖRÖS, M. VARGA, G. PUTIRSKAYA, Nonlinear Phenomena in Chemical Dynamics, C. VIDAL, A. PACAULT (Eds), Springer-Verlag, New York, 1981, p. 207.
R. RAMASWAMY, S. MOHAN, M. KRISHNARATNAM, S. RAMANATHAN, Paper presented at the 3rd Intern. Symp. on Advances in Electrochemical Science and Technology, Madras, December 1984.
S. D. FURROW, R. M. NOYES, J. Am. Chem. Soc., 104 (1982) 42.
J. J. WALTERS, I. M. KOLTHOFF, J. Am. Chem. Soc., 83 (1979) 3056.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Krishnaratnam, M., Viswanathan, B. & Ramaswamy, R. Effect of gamma-irradiation on the uncatalyzed bromate oscillator. Journal of Radioanalytical and Nuclear Chemistry, Articles 120, 353–359 (1988). https://doi.org/10.1007/BF02037349
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02037349