Abstract
The uptake of Na+, K+, Rb+, Cs+, Ag+, Ca2+, Cu2+, Sr2+, Cd2+, Ba2+, Pb2+, Sc3+, Co3+, Y3+, Sb3+, Tb3+, Zr4+ and Th4+ cations at very small concentrations has been studied over a column of stannic phosphate. The exchanger was prepared by mixing H3PO4, NaCl and SnCl4 in suitable proportions and the ratio of P∶Sn, in the product was obtained to be 1.96. Radiochemical separations of carrier free95Zr from234Th and115mIn, from115Cd have been carried out by adopting a simple chemical procedure over a column of stannic phosphate. The γ-spectrum analysis showed that the separated products are of high radionuclidic purity. The separation procedures took less than half an hour with quantitative yield.
Similar content being viewed by others
References
U. COSTANTINO, R. GASPERONI, J. Chromatog., 51 (1970) 289.
E. MERZ, J. Electrochem., 63 (1959) 288.
Y. INOUE, J. Inorg. Nucl. Chem., 26 (1964) 2241.
C. Z. RODDEN, J. C. WARF, Analytical Chemistry of the Manhattan Project, Vol. VIII-1, Chapter-2, McGraw Hill, London, 1950.
J. P. WILLIAMS, H. I. FEINSTEIN, J. RODDEN, Report A-2912, Vol. 1, January 1946, p. 42.
C. J. RODDEN, C. G. GOLDBECK, Report A-2936, October 1946.
G. R. MARTIN, Report MC-113, Feb. 13, 1945.
F. A. GOOCH, M. KOBAYASHI, Am. J. Sci., 45 (1918) 227.
J. A. FAHEY, M. D. FOSTER, Report A-2509, October 1945.
R. J. MEYER, Z. Anorg. Chem., 71, (1911) 65.
F. S. FRIMALDI, J. G. FAIRCHILD, Report A-2507, June 1945.
F. HECHT, Z. Anal. Chem., 75 (1928) 28.
O. RUFF, G. LAUSCHKE, Z. Anorg. Chem., 97 (1916) 108, 110.
E. JACOBI, Helv. Phys. Acta, 22 (1949) 66.
I. J. GRUVERMAN, P. KRUGER, Intern. J. Appl. Radiation Isotopes, 5 (1959) 21.
C. D. CORYELL, N. SUGARMAN, Radiochemical studied. The Fission Products, Book 2, Paper No. 127, McGraw Hill, London, 1951, p. 828.
I. P. ALIMARIN, E. P. TSINTSEVICH, V. P. BURLAKA, Zavodsk. Lab., 25 (1959) 1287.
G. WILKINSON, W. E. GRUMMITT, Nucleonics, 9 (1951) 52.
A. A. SMALES, J. VAN R. SMIT, H. IRVING, Analyst, 82 (1957) 539.
I. STRONSKI, Radiochem. Radioanal Letters, 5 (1970) 113.
D. K. BHATTACHARYYA, S. BASU, J. Radioanal. Chem., 47 (1978) 105.
D. K. BHATTACHARYYA, S. BASU, J. Radioanal Chem., 52 (1979) 267.
O. V. SINGH, S. N. TANDON, J. Radioanal. Chem., 36 (1977) 331.
W. SONAD, A. HAGGAG, J. Radioanal Chem., 43 (1978) 209.
K. R. VERMA, K. B. SHAH, R. S. MANI, Radiochem. Radioanal Letters, 43 (1980) 255.
D. K. BHATTACHARYYA, A. DE J. Radioanal. Chem., 83 (1984) 309.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bhattacharyya, D.K., De A. Role of stannic phosphate in the uptake of cations. Separation of zirconium from thorium and cadmium from indium at tracer concentrations. Journal of Radioanalytical and Nuclear Chemistry, Articles 100, 277–285 (1986). https://doi.org/10.1007/BF02037233
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02037233