Solvent extraction of uranium(VI) by LIX-54 and its mixtures

  • S. Singh
  • V. Chakravortty
  • K. C. Dash
Article

Abstract

Studies on solvent extraction of uranium(VI) by a commercially available chelating extractant LIX-54 (a β-diketone derivative) (HA) and its mixtures with tri-n-butyl phosphate (TBP) in benzene diluent show quantitative extraction by a mixture of 5% LIX-54 and 5% TBP at pH 4.3. Influence of different proportions of LIX-54 or TBP in the mixtures on the extraction of the same metal ion has been studied. Pronounced synergism has been observed. The composition of the extracted species seems to be [UO2(OH)(A)(HA)(TBP)] as determined from slope analysis. Slopes of the linear plots were computed employing regression analysis and variance in results has been shown.

Keywords

Phosphate Physical Chemistry Benzene Inorganic Chemistry Uranium 

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Copyright information

© Akadémiai Kiadó 1988

Authors and Affiliations

  • S. Singh
    • 1
  • V. Chakravortty
    • 1
  • K. C. Dash
    • 1
  1. 1.Department of ChemistryUtkal UniversityBhubaneswar(India)

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