Abstract
The values of Sb(III), Tl(I), Te(IV), and biological substance, DNA determined by sub- and super-equivalence method of isotope dilution analysis (SSE-IDA) and substoichiometric isotope dilution analysis (Subst-IDA) under the same condition were compared. From the results, it was proved that SEE-IDA did not need the strict condition necessary for Subst-IDA and the determination by SEE-IDA was possible within the error of a few percent, and the range of determination was wider than that of Subst-IDA. The various variants of SSE-IDA reported so far were classified into SEE-Reverse-IDA and SEE-Direct-IDA. Finally, the characteristics of SEE-IDA allowing accurate determination were discussed and summarized.
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J. KLAS, J. TÖLGYESSY, E. H. KLEHR, Radiochem. Radioanal. Lett., 18 (1974) 83.
N. SUZUKI, Proc. 2nd Conf. Radioisotopes (Japan), (1958), 151.
I. E. ZIMAKOV, G. S. ROZHAVSKII, Tr. Komis. po Analit. Khim., 9 (1958) 231.
J. RŮŽIČKA, J. STARY, Talanta, 8 (1961) 228.
J. KLAS, J. TÖLGYESSY, J. LESNÝ, Sub-superekvivalentová Izotopová Zriedôvacia Analýza (Sub-superequivalence Isotope Dilution Analysis), Veda, Bratislava, 1985.
H. YOSHIOKA, T. KAMBARA, Talanta, 31 (1984) 509.
H. YOSHIOKA, K. HASEGAWA, Analyst, 112 (1987) 855.
H. YOSHIOKA, T. HISADA, K. YOSHINAGA, K. HASEGAWA, N. IKEDA, Radioisotopes, 36 (1987) 389.
H. HOSHIOKA, Y. MIYAKI, K. HASEGAWA, Analyst (submitted).
J. KLAS, Radiochem. Radioanal Lett., 33 (1978) 31.
J. KLAS, J. TÖLGYESSY, J. LESNÝ, Radiochem. Radioanal. Lett., 30 (1977) 365.
V. R. S. RAO, Ch. PULLA RAO, G. TATAIAH, Radiochem. Radioanal. Lett., 30 (1977) 365.
H. YOSHIOKA, K. HASEGAWA, T. KAMBARA, J. Radioanal. Nucl. Chem., 117 (1987) 47.
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Yoshioka, H., Hasegawa, K. Radioanalytical application of sub- and super-equivalence method of isotope dilution analysis. Journal of Radioanalytical and Nuclear Chemistry, Articles 160, 417–423 (1992). https://doi.org/10.1007/BF02037116
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DOI: https://doi.org/10.1007/BF02037116