Skip to main content
SpringerLink
Log in

Studies on the liquid-liquid extraction and precipitate flotation of the second kind of Co(II) using 8-hydroxy quinoline

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The liquid-liquid extraction and precipitate flotation of the second kind (i.e., without the use of surfactant collectors) have been investigated for Co(II) using 8-hydroxy quinoline (Hq) and the results are compared. Organic solvents used were chloroform in the case of liquid-liquid extraction and ethanol (used as a solvent for the collector and as a frother) in the case of flotation. From the results it appears that liquid-liquid extraction occurs through the formation of the adduct Coq2(Hq) but flotation takes place through the formation of the precipitate Coq2. Unlike precipitate flotation of the first kind, precipitate flotation of the second kind has the advantage that the recovery is not affected by the ionic strength of the medium. An induction time of about 5 minutes is required to attain the maximum flotation results. The effects of pH and Hq concentration on both of the extraction processes were also investigated and the results are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. MOELLER, Ind. Eng. Chem. Anal. Ed., 15 (1943) 346.

    Google Scholar 

  2. I. T. KLIMOV, B. YA. EREMENKO, Gidrokhim. Mat., No. 30 (1960) 175.

    Google Scholar 

  3. H. GOTO, E. SUDO, Japan Analyst, 10 (1961) 463.

    Google Scholar 

  4. D. S. FLETT, Solvent Extr. Met. Processes Proc. Int. Symp. 1972, p. 20.

  5. T. MIZOGUCHI, H. ISHII, Bunseki Kagaku, 26 (1977) 839; C.A.: 89 (1978) 16153f.

    Google Scholar 

  6. J. R. JENNINGS, Can. 1, 025, 670 (CL. 53–310) 07 Feb. 1978.

  7. M. I. BULATOV, N. P. MUKHOVIKOVA, V. F. VASHUKOYA, Izv. Vyssh. Ucheln. Zaved, Khim. Khim. Teckhnol, 21 (1978) 669; C.A.: 89 (1978) 66193j.

    Google Scholar 

  8. K. ABSTSUKA, N. NOBUYAMA, I. ATEUYA, Anal. Sci., 5 (1989) 475.

    Google Scholar 

  9. T. S. LOBANA, P. K. BHATIA, Ind. J. Chem. Sect. A, 30A (1991) 933.

    Google Scholar 

  10. F. UUPMLAND, D. SCHUNEMANN, Angew. Chem., 70 (1958) 403.

    Google Scholar 

  11. K. MOTOJIMA, H. HASHITANI, Japan Analyst, 9 (1960) 151.

    Google Scholar 

  12. F. UMLAND, Z. Anal. Chem., 190 (1962) 186.

    Google Scholar 

  13. J. STARY, Anal. Chim. Acta, 28 (1963) 132.

    Google Scholar 

  14. N. M. KUZ'MIN, YU. A. ZOLOTOV, Russ. J. Inorg. Chem., 11 (1966) 1241.

    Google Scholar 

  15. S. OKI, Anal. Chim. Acta, 50 (1970) 465.

    Google Scholar 

  16. H. AHARWE, H. KAWAMOTO, T. SAITO, Nippon Kagahu Zasshi, 92 (1971) 1156. (Quoted by Ref. 19).

    Google Scholar 

  17. S. OKI, J. TERADA, Anal. Chim. Acta, 61 (1972) 49.

    Google Scholar 

  18. S. OKI, J. TERADA, Anal. Chim. Acta, 66 (1973) 201.

    Google Scholar 

  19. E. SEKIDO, K. FUJITA, Bull. Chem. Soc. Japan, 49 (1976) 3073.

    Google Scholar 

  20. A. T. RANE, K. S. BHATHI, Can. J. Chem., 57 (1979) 580.

    Google Scholar 

  21. P. GUESNET, D. BAUER, J. Chem. Research, Synop., (1981) 127.

  22. A. YUCHI, K. IMAI, H. WODA, M. SHIRO, G. NAKAGAWA, Bull. Chem. Soc. Japan, 59 (1986) 3847.

    Google Scholar 

  23. R. E. BAARSON, C. L. RAY, Precipitate Flotation: A New Metal Extraction and Concentration Technique. Am. Inst. of Mining, Metall. and Pet. Eng. Symp., Dallas, Texas, 1963.

  24. E. J. MAHNE, T. A. PINFOLD, J. Appl. Chem. 18 (1968) 140.

    Google Scholar 

  25. E. J. MAHNE, T. A. PINFOLD, Chem. Ind. (London), 30 (1966) 1299.

    Google Scholar 

  26. T. A. PINFOLD, Precipitate Flotation, Chapter 5 in: Adsorptive Bubbles Separation Techniques, R. LEMLICH (Ed.), Academic Press, New York, 1972.

    Google Scholar 

  27. E. J. MAHNE, T. A. PINFOLD, J. Appl. Chem., 18 (1968) 52.

    Google Scholar 

  28. T. A. PINFOLD, J. SHEIHAM, J. Appl. Chem., 18 (1968) 217.

    Google Scholar 

  29. E. J. MAHNE, T. A. PINFOLD, J. Appl. Chem., 19 (1969) 57.

    Google Scholar 

  30. M. HIRAIDE, A. MIZUIKE, Bull. Chem. Soc. Japan, 48 (1975) 3753.

    Google Scholar 

  31. A. MIZUIKE, M. HIRAIDE, T. SUZUKI, Bunseki Kagaku, 26 (1977) 72; C.A.: 87 (1977) 47645a.

    Google Scholar 

  32. K. SHAKIR, K. BENYAMIN, M. AZIZ, Can. J. Chem., 62 (1984) 51.

    Google Scholar 

  33. A. I. VOGEL, Practical Inorganic Chemistry, 2nd ed., Longman, Enngland, 1959, p. 176.

    Google Scholar 

  34. H. FLASCHKA, Mikrochemie, 39 (1952) 38.

    Google Scholar 

  35. K. SHAKIR, M. AZIZ, J. Appl. Chem. Biotechnol., 27 (1977), 1.

    Google Scholar 

  36. K. SHAKIR, M. AZIZ, Radiochim. Acta, 26 (1979) 13.

    Google Scholar 

  37. K. SHAKIR, M. AZIZ, H. N. SALAMA, K. BENYAMIN, Isotopenprazis, 23 (1987) 30.

    Google Scholar 

  38. K. SHAKIR, M. AZIZ, H. N. SALAMA, K. BENYAMIN, Radiochim. Acta 41 (1987) 47.

    Google Scholar 

  39. F. H. CHOU, O. FERNANDS, H. FREISIR, Anal. Chem., 37 (1965) 361.

    Google Scholar 

  40. M. BOUMEZIOUND, C. TONDRE, J. Chemie Physique, 85 (1988) 719.

    Google Scholar 

  41. A. YUCHI, S. YAMADA, M. TANAKA, Anal. Chim. Acta, 115 (1980) 301.

    Google Scholar 

  42. H. R. FLECH, A. M. WARD, Analyst, 58 (1933) 388.

    Google Scholar 

  43. H. R. FLECH, H. F. J. GREEMANE, A. M. WARD, Analyst, 59 (1934) 325.

    Google Scholar 

  44. K. SHAKIR, M. AZIZ, Tenside Detergents, 15 (1978) 3.

    Google Scholar 

  45. K. SHAKIR, M. AZIZ, K. BENYAMIN, Tenside Surf. Det., 27 (1990) 329.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Radiation Protection and Nuclear Chemistry Departments, Nuclear Research and Hot Laboratories Centres, Atomic Energy Authority, Atomic Energy Post 13759, Cairo, Egupt

    M. Aziz & Sh. G. Beheir

Authors
  1. M. Aziz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Sh. G. Beheir
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aziz, M., Beheir, S.G. Studies on the liquid-liquid extraction and precipitate flotation of the second kind of Co(II) using 8-hydroxy quinoline. Journal of Radioanalytical and Nuclear Chemistry, Articles 196, 35–44 (1995). https://doi.org/10.1007/BF02036287

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02036287

Keywords

Search

Navigation